Physicochemical characteristics of a novel activated carbon produced from tea industry waste

被引:163
作者
Gundogdu, Ali [1 ]
Duran, Celal [2 ]
Senturk, H. Basri [2 ]
Soylak, Mustafa [3 ]
Imamoglu, Mustafa [4 ]
Onal, Yunus [5 ]
机构
[1] Gumushane Univ, Fac Engn & Nat Sci, Dept Food Engn, TR-29100 Gumushane, Turkey
[2] Karadeniz Tech Univ, Dept Chem, Fac Sci, TR-61080 Trabzon, Turkey
[3] Erciyes Univ, Dept Chem, Fac Sci, TR-38039 Kayseri, Turkey
[4] Sakarya Univ, Fac Arts & Sci, Dept Chem, TR-54187 Sakarya, Turkey
[5] Inonu Univ, Dept Chem Engn, Fac Engn, TR-44280 Malatya, Turkey
关键词
Activated carbon; Tea industry waste; Chemical activation; Zinc chloride; Characterization; SOLID-PHASE EXTRACTION; LOW-COST ADSORBENT; CHEMICAL ACTIVATION; AQUEOUS-SOLUTIONS; PORE SYSTEMS; ADSORPTION; REMOVAL; SURFACE; IONS; OPTIMIZATION;
D O I
10.1016/j.jaap.2013.07.008
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Tonnes of waste are generated during tea production in Turkey, one of the black tea producing countries in the world. These wastes are not used for any purposes throughout industrial sector. The objective of this study is to bring in economic value to waste materials by producing activated carbons from wastes of a tea plant and to characterize their physicochemical properties. Three types of activated carbons were produced by chemical activation using zinc chloride from tea industry wastes (TIW). Mesoporous structure and surface area rise as the ratio of ZnCl2/TIW increases. When the ratios of ZnCl2/TIW were selected as 1/2:1, 1:1, and 2:1, mesoporous activated carbons are found in the percentages of 10.9%, 39.9% and 77.7% with BET surface areas of 706, 1066 and 1141 m(2) g(-1), respectively. The resultant activated carbons were characterized by analyses of proximate-ultimate, FT-IR, SEM, TGA, methylene blue-iodine numbers, and surface functional groups. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:249 / 259
页数:11
相关论文
共 56 条
[1]  
Aci F, 2008, FRESEN ENVIRON BULL, V17, P997
[2]  
Adamson A.W., 1967, PHYS CHEM SURFACES, V15
[3]   The preparation of active carbons from coal by chemical and physical activation [J].
Ahmadpour, A ;
Do, DD .
CARBON, 1996, 34 (04) :471-479
[4]   The preparation of activated carbon from macadamia nutshell by chemical activation [J].
Ahmadpour, A ;
Do, DD .
CARBON, 1997, 35 (12) :1723-1732
[5]   Activated Tea Waste as a Potential Low-Cost Adsorbent for the Removal of p-Nitrophenol from Wastewater [J].
Ahmaruzzaman, M. ;
Gayatri, S. Laxmi .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (11) :4614-4623
[6]  
Allen S.J., 1998, DEV CHEM ENG MINERAL, V6, P231, DOI [DOI 10.1002/apj.5500060501, 10.1002/apj.5500060501]
[7]   Thermal degradation of cellulose derivatives/starch blends and sisal fibre biocomposites [J].
Alvarez, VA ;
Vázquez, A .
POLYMER DEGRADATION AND STABILITY, 2004, 84 (01) :13-21
[8]   Removal of phenols from water and petroleum industry refinery effluents by activated carbon obtained from coconut coir pith [J].
Anirudhan, T. S. ;
Sreekumari, S. S. ;
Bringle, C. D. .
ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2009, 15 (5-6) :439-451
[9]  
[Anonymous], 1999, ANN BOOK ASTM STAND, V03.01
[10]  
[Anonymous], 2006, ASTM D 2166Standard test methods for unconfined compressive strength of cohesive soils