The charge transfer characteristic of porphyrin Langmuir-Blodgett films

被引：6

作者：

Qi, P. ^{[1
]}

Li, Z. H. ^{[1
]}

Zhou, Y. ^{[1
]}

Wang, F. ^{[1
]}

Du, Y. ^{[1
]}

Zhang, L. Q. ^{[1
]}

Li, G. ^{[1
]}

Zhang, H. Z. ^{[1
]}

机构：

[1] Jilin Univ, Coll Phys, Changchun 130012, Peoples R China

来源：

APPLIED SURFACE SCIENCE | 2013年 / 279卷

基金：

中国国家自然科学基金;

关键词：

Order; Porphyrin LB films; Charge transfer; Interaction; THIN-FILMS; ELECTROCHEMISTRY; HEMOGLOBIN; ELECTRODES; METAL; DMF;

D O I：

10.1016/j.apsusc.2013.04.098

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ordered porphyrin Langmuir-Blodgett (LB) films were prepared under different surface pressures. The UV-vis absorption spectrum, infrared spectrum, cyclic voltammetry and constant potential jump were used for testing. UV-vis spectra showed that under the surface pressure of approx. 10 mN/m, the ordered porphyrin LB films formed were demonstrated by infrared spectra. With the order degree of LB films strengthened, the charge transfer and storage of porphyrin LB films enhanced. And it was measured by electrochemical method. IR spectrum proves that both the interaction of porphyrin rings (the rings can form the head-to-head structure) and that of hydroxyl groups (the groups can form the feet-to-feet structure) in porphyrin LB ordered films can affect the charge transfer characteristics of porphyrin films. (C) 2013 The Authors. Published by Elsevier B.V. All rights reserved.

引用

页码：349 / 352

页数：4

共 21 条

[1]

Allen J., 2001, ELECTROCHEMICAL METH, P211

[2] ELECTROCHEMISTRY OF A TETRARUTHENATED COBALT PORPHYRIN AND ITS USE IN MODIFIED ELECTRODES AS SENSORS OF REDUCING ANALYTES [J].

ARAKI, K ;

ANGNES, L ;

AZEVEDO, CMN ;

TOMA, HE .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 397 (1-2) :205-210

[3] Fabrication of Langmuir-Blodgett thin films of porphyrins and investigation on their gas sensing properties [J].

Capan, I. ;

Tarimci, C. ;

Capan, R. .

SENSORS AND ACTUATORS B-CHEMICAL, 2010, 144 (01) :126-130

[4] Influence of annealing on the optical properties of 5,10,15,20-tetraphenyl-21H, 23H-porphine iron (III) chloride thin films [J].

El-Nahass, M. M. ;

El-Deeb, A. F. ;

Metwally, H. S. ;

Hassanien, A. M. .

MATERIALS CHEMISTRY AND PHYSICS, 2011, 125 (1-2) :247-251

[5]

Geoffrey J.A., 1999, J MATER CHEM, V9, P1991

[6] Solvent effects on spectrophotometric titrations and vibrational spectroscopy of 5,10,15-triphenyl-20-(4-hydroxyphenyl)porphyrin in aqueoius DMF [J].

Guo, Hongwei ;

Jiang, Junguang ;

Shi, Yingyan ;

Wang, Yuling ;

Dong, Shaojun .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 67 (01) :166-171

[7] Sequential deprotonation of meso-(p-hydroxyphenyl)porphyrins in DMF:: From hyperporphyrins to sodium porphyrin complexes [J].

Guo, HW ;

Jiang, JG ;

Shi, YY ;

Wang, YL ;

Wang, YZ ;

Dong, SJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (01) :587-594

[8] Direct electrochemistry of hemoglobin in egg-phosphatidylcholine films and its catalysis to H2O2 [J].

Han, XJ ;

Huang, WM ;

Jia, JB ;

Dong, SJ ;

Wang, EK .

BIOSENSORS & BIOELECTRONICS, 2002, 17 (09) :741-746

[9]

He Y.N., 1993, J INORGANIC CHEM, V9, P336

[10] Monolayers, Langmuir-Blodgett films of bimetallic coordination polymers of 4′-(4-pyridyl)-2,2′:6′,2"-terpyridine [J].

Liu, Bing ;

Huang, Hong-Xiang ;

Zhang, Chao-Feng ;

Chen, Meng ;

Qian, Dong-Jin .

THIN SOLID FILMS, 2008, 516 (08) :2144-2150

← 1 2 3 →