μ-1,1′-methylenedi-1H-imidazole-κ2N3:N3′-bis[aqua(pyridine-2,6-dicarboxylato)copper(II)] tetrahydrate

被引：10
|
作者：
Dong, GY [1 ]
Cui, GH [1 ]
Wang, SC [1 ]
机构：
[1] Hebei Polytech Unv, Coll Chem Engn & Biotechnol, Tangshan 063009, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806006350
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu-2(C7H3NO4)(2)(C7H8N4)(H2O)(2)]center dot 4H(2)O, has a dinuclear structure in which each Cu-II atom is five-coordinate in a distorted square-based pyramidal geometry and the 1,1'-methylenedi-1H-imidazole ligand adopts a bismonodentate bridging mode, linking the Cu-II atoms. A twofold rotation axis passes through the C atom linking the imidazole rings. The molecules are connected by O-H center dot center dot center dot O hydrogen bonds [O center dot center dot center dot O = 2.748 (3)-2.973 (3) angstrom].
引用
收藏
页码：M606 / M607
页数：2
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