Insight into geometric preferences in uranium(vi) mixed tris(imido) systems

被引：2

作者：

Raghavan, Adharsh ^{[1
]}

Anderson, Nickolas H. ^{[1
]}

Tatebe, Caleb J. ^{[1
]}

Stanley, Dalton A. ^{[1
]}

Zeller, Matthias ^{[1
]}

Bart, Suzanne C. ^{[1
]}

机构：

[1] Purdue Univ, Dept Chem, WC Brown Lab, W Lafayette, IN 47907 USA

来源：

CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 75期

基金：

美国国家科学基金会;

关键词：

INVERSE TRANS INFLUENCE; IMIDO ANALOGS; COMPLEXES; FAMILY;

D O I：

10.1039/d0cc03261a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Uranium tris(imido) species have been synthesized using different imido groups in the axial and equatorial positions by treating [((PDIMe)-P-Mes)U(THF)](2)(1-THF), which is a uranium(iv) dimer that is supported by(Mes)PDI(Me)tetraanions, with mixed organoazide solutions. While the origin of the geometric preference isn't clear, both steric and electronic factors are likely at play.

引用

页码：11138 / 11141

页数：4

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