Carbon-based electrocatalysts for advanced energy conversion and storage

被引：618
作者：
Zhang, Jintao [1 ]
Xia, Zhenhai [2 ]
Dai, Liming [1 ]
机构：
[1] Case Western Reserve Univ, Dept Macromol Sci & Engn, Ctr Adv Sci & Engn Carbon Case4Carbon, Cleveland, OH 44106 USA
[2] Univ North Texas, Dept Mat Sci & Engn, Dept Chem, Denton, TX 76203 USA
来源：
SCIENCE ADVANCES | 2015年 / 1卷 / 07期
基金：
美国国家科学基金会;
关键词：
METAL-FREE ELECTROCATALYSTS; OXYGEN REDUCTION REACTION; NITROGEN-DOPED GRAPHENE; ORDERED MESOPOROUS CARBONS; COVALENT ORGANIC POLYMERS; FUEL-CELLS; CATHODE CATALYSTS; GRAPHITIC CARBON; O-2; REDUCTION; EFFICIENT ELECTROCATALYSTS;
D O I：
10.1126/sciadv.1500564
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) play curial roles in electrochemical energy conversion and storage, including fuel cells and metal-air batteries. Having rich multidimensional nanoarchitectures [ for example, zero-dimensional (0D) fullerenes, 1D carbon nanotubes, 2D graphene, and 3D graphite] with tunable electronic and surface characteristics, various carbon nanomaterials have been demonstrated to act as efficient metal-free electrocatalysts for ORR and OER in fuel cells and batteries. We present a critical review on the recent advances in carbon-based metal-free catalysts for fuel cells and metal-air batteries, and discuss the perspectives and challenges in this rapidly developing field of practical significance.
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页数：19
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