Terminal Modification with 1-Adamantylamine to Endow Hyperbranched Polyamidoamine with Thermo-/pH-Responsive Properties

被引：36

作者：

Guo, Zhe ^{[1
]}

Zhang, Yongwen ^{[1
]}

Huang, Wei ^{[1
]}

Zhou, Yongfeng ^{[1
]}

Yan, Deyue ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2008年 / 29卷 / 21期

基金：

中国国家自然科学基金;

关键词：

1-adamantylamine; hyperbranched; LCST; polyamidoamines; stimuli-sensitive polymers;

D O I：

10.1002/marc.200800450

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A novel terminal modification agent to endow hyperbranched polyamidoamine (HPAMAM) with thermo-/pH-responsive properties is reported. HPAMAM with terminal vinyl groups is first synthesized and then end-capped by 1-adamantylamine (ADA). The resulting hyperbranched polymer (HPAMAM-ADA) shows interesting thermo-responsive properties in aqueous solution, which have been investigated by UV-vis spectroscopy, optical microscopy, and H-1 NMR spectroscopy. The lower critical solution temperature can be controlled by adjusting the end-capping ratio of ADA. In addition, HPAMAM-ADA exhibits a pH-dependent water solubility. This pH-responsive behavior is also studied.

引用

页码：1746 / 1751

页数：6

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