{Ph2(Carb)P}MCl3 (M = Pd, Pt; Carb=2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) -: a novel cationic phosphane ligand

被引：0
|
作者：
Kuhn, N
Göhner, M
Henkel, G
机构：
[1] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany
[2] Univ Duisburg Gesamthsch, Inst Synth Chem, D-4100 Duisburg, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1999年 / 625卷 / 09期
关键词：
carbenes; phosphorus; palladium; platinum; crystal structure;
D O I：
10.1002/(SICI)1521-3749(199909)625:9<1415::AID-ZAAC1415>3.0.CO;2-3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The phosphane ligand [Ph-2(Carb)P](+) forms neutral complexes {Ph-2(Carb)P}MCl3 (Carb = 2,3-dihydro-1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene; M = Pd, Pt) through the reaction of it's chloride salt with (PhCN)(2)MCl2; the triarylphosphane type properties of the ligand are revealed by n.m.r. and structural data.
引用
收藏
页码：1415 / 1416
页数：2
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