Electrospun polyimide nanofiber-based nonwoven separators for lithium-ion batteries

被引：381

作者：

Miao, Yue-E ^{[1
]}

Zhu, Guan-Nan ^{[2
,3
]}

Hou, Haoqing ^{[4
]}

Xia, Yong-Yao ^{[2
,3
]}

Liu, Tianxi ^{[1
]}

机构：

[1] Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China

[2] Fudan Univ, Dept Chem, Inst New Energy, Shanghai 200433, Peoples R China

[3] Fudan Univ, Shanghai Key Lab Mol Catalysis & Innovat Mat, Inst New Energy, Shanghai 200433, Peoples R China

[4] Jiangxi Normal Univ, Dept Chem & Chem Engn, Nanchang 330022, Peoples R China

来源：

JOURNAL OF POWER SOURCES | 2013年 / 226卷

基金：

中国国家自然科学基金;

关键词：

Polyimide; Electrospinning; Nonwoven separator; Lithium-ion battery; POLYMER ELECTROLYTES; LI; MEMBRANES; PERFORMANCES; CONVERSION; STORAGE; PVDF;

D O I：

10.1016/j.jpowsour.2012.10.027

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Polyimide (PI) nanofiber-based nonwovens have been fabricated via electrospinning for the separators of lithium-ion batteries (LIBs). Differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and hot oven tests show that the PI nanofiber-based nonwovens are thermally stable at a high temperature of 500 degrees C while the commercial Celgard membrane exhibits great shrinkage at 150 degrees C and even goes melting over 167 degrees C, indicating a superior thermal stability of PI nanofiber-based nonwovens than that of the Celgard membrane. Moreover, the PI nanofiber-based nonwovens exhibit better wettability for the polar electrolyte compared to the Celgard membrane. The PI nanofiber-based nonwoven separators are also evaluated to have higher capacity, lower resistance and higher rate capability compared to the Celgard membrane separator, which proves that they are ideal candidates for separators of high-performance rechargeable LIBs. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：82 / 86

页数：5

共 50 条

[21] Fabrication and post-processing of PI/PVDF-HFP/PI electrospun sandwich separators for lithium-ion batteries [J].

Parsaei, Solmaz ;

Zebarjad, Seyed Mojtaba ;

Moghim, Mohammad Hadi .

POLYMER ENGINEERING AND SCIENCE, 2022, 62 (11) :3641-3651

[22] Safety assessment of polyolefin and nonwoven separators used in lithium-ion batteries [J].

Wang, Ethan ;

Chiu, Chao-Hung ;

Chou, Po-Heng .

JOURNAL OF POWER SOURCES, 2020, 461

[23] Poly(vinylidene fluoride)/SiO2 composite membranes prepared by electrospinning and their excellent properties for nonwoven separators for lithium-ion batteries [J].

Zhang, Feng ;

Ma, Xilan ;

Cao, Chuanbao ;

Li, Jili ;

Zhu, Youqi .

JOURNAL OF POWER SOURCES, 2014, 251 :423-431

[24] Fabrication and Characterization of SiO2/PVDF Composite Nanofiber-Coated PP Nonwoven Separators for Lithium-Ion Batteries [J].

Yanilmaz, Meltem ;

Chen, Chen ;

Zhang, Xiangwu .

JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2013, 51 (23) :1719-1726

[25] Electrospun MXene/polyimide nanofiber composite separator for enhancing thermal stability and ion transport of lithium-ion batteries [J].

Wu, Yitian ;

Wei, Wenhui ;

Feng, Tianxue ;

Li, Wenwen ;

Wang, Xiaoyu ;

Wu, Tao ;

Zhang, Xingshuang .

FRONTIERS IN CHEMISTRY, 2025, 13

[26] Electrospun nanofiber membrane of dibenzo 14-crown-4-ether polyimide for efficient selective lithium recovery from discarded lithium-ion batteries [J].

Yang, Feidong ;

Li, Lei ;

Hua, Junyuan ;

He, Jintao ;

Ma, Xiaohua ;

Li, Jianxin .

SEPARATION AND PURIFICATION TECHNOLOGY, 2024, 334

[27] Core-Shell Structured Polyimide@?-Al2O3 Nanofiber Separators for Lithium-Ion Batteries [J].

Chen, Yuluo ;

Luo, Jinpeng ;

Xu, Hang ;

Hou, Xinran ;

Gong, Man ;

Yang, Changshu ;

Liu, HuiCong ;

Wei, Xiuqin ;

Zhou, Lang ;

Yin, Chuanqiang ;

Li, Xiaomin .

ACS APPLIED ENERGY MATERIALS, 2023, 6 (03) :1692-1701

[28] Engineering of electrospun polyimide separators for electrical double-layer capacitors and lithium-ion cells [J].

Pai, Jui-Yu ;

Hsieh, Cheng-Ta ;

Lee, Chih-Hung ;

Wang, Jeng-An ;

Ku, Hao-Yu ;

Huang, Chun-Lung ;

Hardwick, Laurence J. ;

Hu, Chi-Chang .

JOURNAL OF POWER SOURCES, 2021, 482

[29] Polyvinylidene fluoride nanofiber coated polypropylene nonwoven fabric as a membrane for lithium-ion batteries [J].

Davoud Amini ;

Erfan Oliaei ;

Mehdi Rajabi-Hamane ;

Hossein Mahdavi .

Fibers and Polymers, 2017, 18 :1561-1567

[30] Electrospun nanofiber-coated separator membranes for lithium-ion rechargeable batteries [J].

Lee, Hun ;

Alcoutlabi, Mataz ;

Watson, Jill V. ;

Zhang, Xiangwu .

JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 129 (04) :1939-1951

← 1 2 3 4 5 →