Crystal Structure and Ferroelectric Properties of Poly(vinylidene fluoride)-Carbon nano tube Nanocomposite Film

被引:32
作者
Lee, Ji Seok [1 ,2 ,3 ,4 ,5 ]
Kim, Gwang Ho [1 ,6 ]
Kim, Woo Nyon [6 ]
Oh, Kyung Hwan [2 ,3 ,4 ,5 ]
Kim, Hyeong Tae [1 ]
Hwang, Seung Sang [1 ]
Hong, Soon Man [1 ]
机构
[1] Korea Inst Sci & Technol, Hybrid Mat Res Ctr, Seoul 136791, South Korea
[2] Seoul Natl Univ, Sch Mat Sci & Engn, Seoul, South Korea
[3] Seoul Natl Univ, Sch Mat Sci, Seoul, South Korea
[4] Seoul Natl Univ, Sch Engn, Seoul, South Korea
[5] Seoul Natl Univ, Res Inst Adv Mat, Seoul, South Korea
[6] Korea Univ, Dept Biol & Chem Engn, Seoul, South Korea
关键词
carbon nano tube; ferroelectric properties; nano-composite; poly(vinylidene fluoride);
D O I
10.1080/15421400802330861
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We investigated the effect of carbon nanotube on the crystal structure and mechanical/ferroelectric/piezoelectric properties based on poly(vinylidene fluoride) (PVDF) and carbon nano tube (CNT) composite film. The composite films were prepared by solution blending method, and the films were formed by hot-pressing. The contents of CNT were from 0.001wt.% to 1wt.%. For inducing piezoelectric beta-crystal structure, the hot-pressed nano composite films were drawn by 400% elongation. These samples were poled at high voltage and high temperature for polarization of the PVDF/CNT composite film. The beta-crystalline phase were increased with CNT contents, passing through the peak, and decreased. The structural changes depend on the CNT contents, drawing and poling conditions.
引用
收藏
页码:247 / 254
页数:8
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