Synthesis, Structure, Tautomerism, and Reactivity of Methanetrisamidines

被引：7

作者：

Gutschank, Benjamin ^{[1
]}

Schulz, Stephan ^{[1
]}

Marcinkowski, Michael ^{[1
]}

Jansen, Georg ^{[1
]}

Bandmann, Heinz ^{[1
]}

Blaeser, Dieter ^{[1
]}

Woelper, Christoph ^{[1
]}

机构：

[1] Univ Duisburg Essen, Fak Chem, D-45117 Essen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 43期

关键词：

ab initio calculations; structure determination; tautomerism; X-ray diffraction; BASIS-SETS; COORDINATION CHEMISTRY; CRYSTAL-STRUCTURES; AMIDINES; LIGAND; DERIVATIVES; COMPLEXES; ROUTE; NMR;

D O I：

10.1002/anie.201205030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tout au contraire: Both tautomeric forms of a methanetrisamidine were structurally characterized for the first time by X-ray diffraction and by ab initio calculations (see structures; gray C, red H, blue N). Their reactivity as proton acceptors and multianionic ligands was demonstrated. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10893 / 10897

页数：5

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