Quality of the rare earth aluminum borate crystals for laser applications, probed by high-resolution spectroscopy of the Yb3+ ion

被引:26
作者
Boldyrev, K. N. [1 ]
Popova, M. N. [1 ]
Bettinelli, M. [2 ,3 ]
Temerov, V. L. [4 ]
Gudim, I. A. [4 ]
Bezmaternykh, L. N. [4 ]
Loiseau, P. [5 ]
Aka, G. [5 ]
Leonyuk, N. I. [6 ]
机构
[1] RAS, Inst Spect, Troitsk 142190, Moscow Region, Russia
[2] Univ Verona, Dept Biotechnol, I-37134 Verona, Italy
[3] UdR Verona, INSTM, I-37134 Verona, Italy
[4] RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[5] ENSCP, CNRS, LCMCP, UMR 7574, F-75005 Paris, France
[6] Moscow MV Lomonosov State Univ, Fac Geol, Moscow 119899, Russia
基金
俄罗斯基础研究基金会;
关键词
Ytterbium; Aluminum borates; Impurities; High-resolution spectroscopy; UV edge; GROWTH; Y1-XYBXAL3(BO3)(4); LUMINESCENCE; FREQUENCY; CENTERS;
D O I
10.1016/j.optmat.2012.05.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A comparative study was performed of the low-temperature high-resolution absorption spectra of the Yb3+ probe in R1-xYbxAl3(BO3)(4) (R = Y, Tm, Lu) crystals grown by flux technique independently in four different laboratories using different solvents. We show that the incorporation of solvent components into the crystal in the course of crystallization gives rise to spectral satellites of the Yb3+ 0(F-2(7/2)) -> 0'(F-2(5/2)) absorption lines and assign particular satellites to the Yb3+ centers near the bismuth and molybdenum impurities (which decrease the transparency of YAB in the UV spectral range). We suggest this spectroscopic method for a rapid analysis of the quality of UV laser crystals and for improvement of growth technologies. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:1885 / 1889
页数:5
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