Solvothermal synthesis of flower-like Cu2ZnSnS4 nanostructures and their application as anode materials for lithium-ion batteries

被引：46

作者：

Zhou, Wen-Hui ^{[1
]}

Zhou, Yan-Li ^{[1
]}

Feng, Jun ^{[1
]}

Zhang, Ji-Wei ^{[1
]}

Wu, Si-Xin ^{[1
]}

Guo, Xiu-Chun ^{[2
]}

Cao, Xuan ^{[3
]}

机构：

[1] Henan Univ, Key Lab Special Funct Mat MOE, Kaifeng 475004, Peoples R China

[2] Henan Univ, Pharmaceut Coll, Kaifeng 475004, Peoples R China

[3] Shandong Acad Sci, Inst Oceanog Instrumentat, Qingdao 266061, Peoples R China

来源：

CHEMICAL PHYSICS LETTERS | 2012年 / 546卷

基金：

中国国家自然科学基金;

关键词：

ELECTRODE MATERIALS; STORAGE CAPACITY; CAPABILITY; CHALLENGES; SNS2;

D O I：

10.1016/j.cplett.2012.07.060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this Letter, flower-like Cu2ZnSnS4 (CZTS) nanostructures were synthesized by solvothermal method. SEM and TEM images revealed that these flower-like CZTS nanostructures are constructed from nanosheets with thickness of about 25 nm. When used as anode materials, these flower-like CZTS exhibited stable lithium-ion insertion/extraction reversibility and long cycle life. The electrochemical performance could be attributed to their hierarchical nanostructure as well as the efficient charge transport induced by Cu and/or Zn. The electrochemical properties of these flower-like CZTS nanostructures implied its potential application as anode materials in the next generation lithium-ion batteries. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.

引用

页码：115 / 119

页数：5

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