Synthesis of graphene oxide/polyimide mixed matrix membranes for desalination

被引:66
作者
Feng, Bo [1 ]
Xu, Kai [1 ]
Huang, Aisheng [1 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Inst New Energy Technol, 1219 Zhongguan Rd, Ningbo 315201, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
CARBON NANOTUBE MEMBRANES; OXIDE MEMBRANES; COMPOSITE MEMBRANES; HOLLOW FIBERS; WATER; GAS; DEHYDRATION; STABILITY; NANOPLATELETS; POLYSULFONE;
D O I
10.1039/c6ra24974d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanohybrid graphene oxide (GO)/polyimide (PI) mixed matrix membranes (MMMs) were prepared by dispersing GO into PI through wet phase inversion method. The structure of GO/PI MMMs was characterized by using XRD, FT-IR and XPS. FESEM was used to analyze the morphology of the GO/PI MMMs. The hydrophilicity of the GO/PI MMMs was determined by static water contact angles. The performances of the GO/PI MMMs were evaluated for desalination of seawater through pervaporation. The GO/PI MMMs display excellent water permeability and salt rejection for desalination of different concentrations of seawater. At 90 degrees C, the GO/PI MMMs exhibit a high water flux (36.1 kg m(-2) h(-1)) and a high salt rejection (99.9%). Further, the GO/PI MMM displays a high stability for seawater desalination. This high separation performance combined with high stability and facile fabrication route recommend the developed GO/PI MMMs as a promising candidate for desalination of seawater.
引用
收藏
页码:2211 / 2217
页数:7
相关论文
共 58 条
  • [11] Enhanced hydrophilicity and salt rejection study of graphene oxide-polysulfone mixed matrix membrane
    Ganesh, B. M.
    Isloor, Arun M.
    Ismail, A. F.
    [J]. DESALINATION, 2013, 313 : 199 - 207
  • [12] THE SEARCH FOR A CHLORINE-RESISTANT REVERSE-OSMOSIS MEMBRANE
    GLATER, J
    HONG, SK
    ELIMELECH, M
    [J]. DESALINATION, 1994, 95 (03) : 325 - 345
  • [13] Characterization of polyethersulfone/polyimide blend membranes prepared by a dry/wet phase inversion: Precipitation kinetics, morphology and gas separation
    Han, Junyoung
    Lee, Wonseok
    Choi, Jae Min
    Patel, Rajkumar
    Min, Byoung-Ryul
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2010, 351 (1-2) : 141 - 148
  • [14] Solid-state NMR studies of the structure of graphite oxide
    He, HY
    Riedl, T
    Lerf, A
    Klinowski, J
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (51) : 19954 - 19958
  • [15] Mixed-Matrix Membrane Hollow Fibers of Cu3(BTC)2 MOF and Polyimide for Gas Separation and Adsorption
    Hu, Jun
    Cai, Hongpei
    Ren, Huiqing
    Wei, Yongming
    Xu, Zhengliang
    Liu, Honglai
    Hu, Ying
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (24) : 12605 - 12612
  • [16] Ultra-Robust Graphene Oxide-Silk Fibroin Nanocomposite Membranes
    Hu, Kesong
    Gupta, Maneesh K.
    Kulkarni, Dhaval D.
    Tsukruk, Vladimir V.
    [J]. ADVANCED MATERIALS, 2013, 25 (16) : 2301 - 2307
  • [17] Graphene Oxide Membranes with Tunable Semipermeability in Organic Solvents
    Huang, Liang
    Li, Yingru
    Zhou, Qinqin
    Yuan, Wenjing
    Shi, Gaoquan
    [J]. ADVANCED MATERIALS, 2015, 27 (25) : 3797 - 3802
  • [18] PREPARATION OF GRAPHITIC OXIDE
    HUMMERS, WS
    OFFEMAN, RE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) : 1339 - 1339
  • [19] Nanostructured materials for water desalination
    Humplik, T.
    Lee, J.
    O'Hern, S. C.
    Fellman, B. A.
    Baig, M. A.
    Hassan, S. F.
    Atieh, M. A.
    Rahman, F.
    Laoui, T.
    Karnik, R.
    Wang, E. N.
    [J]. NANOTECHNOLOGY, 2011, 22 (29)
  • [20] Cross-Linking with Diamine Monomers To Prepare Composite Graphene Oxide-Framework Membranes with Varying d-Spacing
    Hung, Wei-Song
    Tsou, Chi-Hui
    De Guzman, Manuel
    An, Quan-Fu
    Liu, Ying-Ling
    Zhang, Ya-Ming
    Hu, Chien-Chieh
    Lee, Kueir-Rarn
    Lai, Juin-Yih
    [J]. CHEMISTRY OF MATERIALS, 2014, 26 (09) : 2983 - 2990