Synthesis of graphene oxide/polyimide mixed matrix membranes for desalination

被引:68
作者
Feng, Bo [1 ]
Xu, Kai [1 ]
Huang, Aisheng [1 ]
机构
[1] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Inst New Energy Technol, 1219 Zhongguan Rd, Ningbo 315201, Zhejiang, Peoples R China
基金
中国国家自然科学基金;
关键词
CARBON NANOTUBE MEMBRANES; OXIDE MEMBRANES; COMPOSITE MEMBRANES; HOLLOW FIBERS; WATER; GAS; DEHYDRATION; STABILITY; NANOPLATELETS; POLYSULFONE;
D O I
10.1039/c6ra24974d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanohybrid graphene oxide (GO)/polyimide (PI) mixed matrix membranes (MMMs) were prepared by dispersing GO into PI through wet phase inversion method. The structure of GO/PI MMMs was characterized by using XRD, FT-IR and XPS. FESEM was used to analyze the morphology of the GO/PI MMMs. The hydrophilicity of the GO/PI MMMs was determined by static water contact angles. The performances of the GO/PI MMMs were evaluated for desalination of seawater through pervaporation. The GO/PI MMMs display excellent water permeability and salt rejection for desalination of different concentrations of seawater. At 90 degrees C, the GO/PI MMMs exhibit a high water flux (36.1 kg m(-2) h(-1)) and a high salt rejection (99.9%). Further, the GO/PI MMM displays a high stability for seawater desalination. This high separation performance combined with high stability and facile fabrication route recommend the developed GO/PI MMMs as a promising candidate for desalination of seawater.
引用
收藏
页码:2211 / 2217
页数:7
相关论文
共 58 条
[1]   Graphene oxide membranes on ceramic hollow fibers - Microstructural stability and nanofiltration performance [J].
Aba, Nor Farah Diana ;
Chong, Jeng Yi ;
Wang, Bo ;
Mattevi, Cecilia ;
Li, K. .
JOURNAL OF MEMBRANE SCIENCE, 2015, 484 :87-94
[2]   Natural zeolite clinoptilolite-phosphate composite Membranes for water desalination by pervaporation [J].
An, W. ;
Zhou, X. ;
Liu, X. ;
Chai, P. W. ;
Kuznicki, T. ;
Kuznicki, S. M. .
JOURNAL OF MEMBRANE SCIENCE, 2014, 470 :431-438
[3]   Tuning nanostructure of graphene oxide/polyelectrolyte LbL assemblies by controlling pH of GO suspension to fabricate transparent and super gas barrier films [J].
Chen, Jung-Tsai ;
Fu, Ywu-Jang ;
An, Quan-Fu ;
Lo, Shen-Chuan ;
Huang, Shu-Hsien ;
Hung, Wei-Song ;
Hu, Chien-Chieh ;
Lee, Kueir-Rarn ;
Lai, Juin-Yih .
NANOSCALE, 2013, 5 (19) :9081-9088
[4]   Designing carbon nanotube membranes for efficient water desalination [J].
Corry, Ben .
JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (05) :1427-1434
[5]   Carbon nanotube membranes for water purification: A bright future in water desalination [J].
Das, Rasel ;
Ali, Md Eaqub ;
Abd Hamid, Sharifah Bee ;
Ramakrishna, Seeram ;
Chowdhury, Zaira Zaman .
DESALINATION, 2014, 336 :97-109
[6]   MOF based MMMs with enhanced selectivity due to hindered linker distortion [J].
Diestel, Lisa ;
Wang, Nanyi ;
Schwiedland, Baerbel ;
Steinbach, Frank ;
Giese, Ulrich ;
Caro, Juergen .
JOURNAL OF MEMBRANE SCIENCE, 2015, 492 :181-186
[7]   Seawater desalination performance of MFI type membranes made by secondary growth [J].
Duke, Mikel C. ;
O'Brien-Abraham, Jessica ;
Milne, Nicholas ;
Zhu, Bo ;
Lin, Jerry Y. S. ;
da Costa, Joao C. Diniz .
SEPARATION AND PURIFICATION TECHNOLOGY, 2009, 68 (03) :343-350
[8]   Piezoelectric β-polymorph formation and properties enhancement in graphene oxide - PVDF nanocomposite films [J].
El Achaby, M. ;
Arrakhiz, F. Z. ;
Vaudreuil, S. ;
Essassi, E. M. ;
Qaiss, A. .
APPLIED SURFACE SCIENCE, 2012, 258 (19) :7668-7677
[9]   Cellulose membranes for reverse osmosis Part I. RO cellulose acetate membranes including a composite with polypropylene [J].
El-Saied, H ;
Basta, AH ;
Barsoum, BN ;
Elberry, MM .
DESALINATION, 2003, 159 (02) :171-181
[10]   Covalent synthesis of three-dimensional graphene oxide framework (GOF) membrane for seawater desalination [J].
Feng, Bo ;
Xu, Kai ;
Huang, Aisheng .
DESALINATION, 2016, 394 :123-130