Catalysis with Anion-π Interactions

被引：153
|
作者：
Zhao, Yingjie [1 ]
Domoto, Yuya [1 ]
Orentas, Edvinas [1 ]
Beuchat, Cesar [1 ]
Emery, Daniel [1 ]
Mareda, Jiri [1 ]
Sakai, Naomi [1 ]
Matile, Stefan [1 ]
机构：
[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 38期
基金：
欧洲研究理事会;
关键词：
kinetics; molecular recognition; noncovalent interactions; organocatalysis; transition states; MAIN-GROUP THERMOCHEMISTRY; NONCOVALENT INTERACTIONS; RING; ENZYME; TRANSPORT; KINETICS;
D O I：
10.1002/anie.201305356
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The conclusion is inevitable: Increasing stabilization of an anionic transition state with increasing π-acidity of the catalyst is observed; thus, anion-π interactions can contribute to catalysis. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：9940 / 9943
页数：4
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