Catalysis with Anion-π Interactions

被引：153

作者：

Zhao, Yingjie ^{[1
]}

Domoto, Yuya ^{[1
]}

Orentas, Edvinas ^{[1
]}

Beuchat, Cesar ^{[1
]}

Emery, Daniel ^{[1
]}

Mareda, Jiri ^{[1
]}

Sakai, Naomi ^{[1
]}

Matile, Stefan ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 38期

基金：

欧洲研究理事会;

关键词：

kinetics; molecular recognition; noncovalent interactions; organocatalysis; transition states; MAIN-GROUP THERMOCHEMISTRY; NONCOVALENT INTERACTIONS; RING; ENZYME; TRANSPORT; KINETICS;

D O I：

10.1002/anie.201305356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The conclusion is inevitable: Increasing stabilization of an anionic transition state with increasing π-acidity of the catalyst is observed; thus, anion-π interactions can contribute to catalysis. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9940 / 9943

页数：4

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