Enhancement in electro-strain behavior by La3+ substitution in lead free BaZr0.05Ti0.95O3 ceramics

被引:29
作者
Mahajan, Sandeep [1 ]
Haridas, Divya [2 ]
Sreenivas, K. [3 ]
Thakur, O. P. [4 ]
Prakash, Chandra [5 ]
机构
[1] C MET, Hyderabad 500051, Andhra Pradesh, India
[2] Keshav Mahavidyalaya, Delhi 110034, India
[3] Univ Delhi, Dept Phys & Astrophys, Delhi 110054, India
[4] Solid State Phys Lab, Electroceram Grp, Delhi 110054, India
[5] DRDO Bhawan, Directorate Extramural Res & Intellectual Propert, New Delhi 110011, India
关键词
Ceramics; BZT; XRD; Piezoelectric materials; Strain; DIELECTRIC-PROPERTIES; PIEZOELECTRIC PROPERTIES;
D O I
10.1016/j.matlet.2013.01.057
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Recently, lead-free piezoelectric ceramics have widely attracted interest among the research community, as they are considered to be potential substitutes for lead-based ceramics which causes environmental pollution due to the presence of hazardous lead oxide in them. In the present study we have synthesized La doped Ba1-x/2Lax/3(ZryTi1-y)O-3 (x=0-0.06 in steps of 0.02; y=0, 0.05) ceramics by the conventional solid-state reaction method. Results reveal that electric field induced strain increases from similar to 0.08% to similar to 0.18% (at 40 kV/cm applied field) for x=0.02 and y=0.05 of lanthanum and zirconium substitution respectively compared to undoped BaTiO3. It was also observed that, sample with 2 mol% lanthanum could sustain higher electric field upto 120 kV/cm during strain measurement (without electrical breakdown) and results showed highest strain value of similar to 0.3% in this system. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:40 / 43
页数:4
相关论文
共 32 条
[11]  
Mahajan S, 2010, INT FERROELECTRICS, V119, P1
[12]   Ferroelectric relaxor behaviour and impedance spectroscopy of Bi2O3-doped barium zirconium titanate ceramics [J].
Mahajan, Sandeep ;
Thakur, O. P. ;
Bhattacharya, D. K. ;
Sreenivas, K. .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2009, 42 (06)
[13]   Study of Structural and Electrical Properties of Conventional Furnace and Microwave-Sintered BaZr0.10Ti0.90O3 Ceramics [J].
Mahajan, Sandeep ;
Thakur, Om P. ;
Bhattacharya, Dilip K. ;
Sreenivas, Kondapudy .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2009, 92 (02) :416-423
[14]   A comparative study of Ba0.95Ca0.05Zr0.25Ti0.75O3 relaxor ceramics prepared by conventional and microwave sintering techniques [J].
Mahajan, Sandeep ;
Thakur, O. P. ;
Bhattacharya, D. K. ;
Sreenivas, K. .
MATERIALS CHEMISTRY AND PHYSICS, 2008, 112 (03) :858-862
[15]   Structure-property phase diagram of BaZrxTi1-xO3 system [J].
Maiti, Tanmoy ;
Guo, R. ;
Bhalla, A. S. .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2008, 91 (06) :1769-1780
[16]   STRUCTURAL AND DIELECTRIC STUDIES IN THE SYSTEM (BA, CA) (TI, ZR)O3 [J].
MCQUARRIE, M ;
BEHNKE, FW .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1954, 37 (11) :539-543
[17]   Ferroelectric and dielectric properties of vanadium-doped Ba(Ti0.90Zr0.10)O3 ceramics [J].
Moura, F. ;
Simoes, A. Z. ;
Cavalcante, L. S. ;
Zaghete, M. A. ;
Varela, J. A. ;
Longo, E. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 466 (1-2) :L15-L18
[18]   Strain and vacancy cluster behavior of vanadium and tungsten-doped Ba[Zr0.10Ti0.90]O3 ceramics [J].
Moura, F. ;
Simoes, A. Z. ;
Cavalcante, L. S. ;
Zampieri, M. ;
Varela, J. A. ;
Longo, E. ;
Zaghete, M. A. ;
Simoes, M. L. .
APPLIED PHYSICS LETTERS, 2008, 92 (03)
[19]  
Nagata H, 2005, CERAM TRANS, V167, P213
[20]   Synthesis and characterization of A-site deficient rare-earth doped BaZrxTi1-xO3 perovskite-type compounds [J].
Ostos, C. ;
Mestres, L. ;
Matinez-Sarrion, M. L. ;
Garcia, J. E. ;
Albareda, A. ;
Perez, R. .
SOLID STATE SCIENCES, 2009, 11 (05) :1016-1022