Facile synthesis, sensor activity and logic behaviour of 4-aryloxy substituted 1,8-naphthalimide

被引：45

作者：

Marinova, Nevena V. ^{[1
]}

Georgiev, Nikolai I. ^{[1
]}

Bojinov, Vladimir B. ^{[1
]}

机构：

[1] Univ Chem Technol & Met, Dept Organ Synth, BU-1756 Sofia, Bulgaria

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2013年 / 254卷

基金：

美国国家科学基金会;

关键词：

1,8-Naphthalimide; Fluorescence; Fluorescent sensor; Photoinduced electron transfer (PET); Molecular logic; PHOTOINDUCED ELECTRON-TRANSFER; TRANSITION-METAL IONS; BLUE; DERIVATIVES; CHEMOSENSOR; DESIGN; DYES; NAPHTHALIMIDE; SWITCH; GREEN;

D O I：

10.1016/j.jphotochem.2013.01.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of 4-phenoxy- and 4-alkoxy-1,8-naphthalimide fluorophores have been synthesized in high yields at room temperature applying novel facile synthesis. One of the compounds was designed as a fluorescent PET sensor according to the "fluorophore-spacer-receptor" model. The ability of this molecule to detect protons and transition metal cations with pronounced selectivity towards Fe3+ was demonstrated. Moreover the 4-phenoxy substituted 1,8-naphthalimides were highly solvent sensitive and able to detect small quantities of water. The potential of the 1,8-naphthalimide sensor to execute INHIBIT logic function at molecular level was also demonstrated. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：54 / 61

页数：8

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