Synthesis of Nitrogen-Doped Porous Carbon Nanofibers as an Efficient Electrode Material for Supercapacitors

被引:1601
作者
Chen, Li-Feng [1 ]
Zhang, Xu-Dong [1 ]
Liang, Hai-Wei [1 ]
Kong, Mingguang [2 ]
Guan, Qing-Fang [1 ]
Chen, Ping [1 ]
Wu, Zhen-Yu [1 ]
Yu, Shu-Hong [1 ,2 ]
机构
[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Chem,Dept Mat Sci & Engn, Natl Synchrotron Radiat Lab,Div Nanomat & Chem, Hefei 230026, Peoples R China
[2] Chinese Acad Sci, Key Lab Mat Phys, Inst Solid State Phys, Hefei 230031, Peoples R China
基金
中国国家自然科学基金; 对外科技合作项目(国际科技项目);
关键词
nitrogen-doped porous carbon nanofibers; scale-up production; electrode material; supercapacitors; ADVANCED ENERGY-CONVERSION; ELECTROCHEMICAL PERFORMANCE; MESOPOROUS CARBON; HYDROTHERMAL CARBONIZATION; NANOTUBES; STORAGE; POLYPYRROLE; CAPACITANCE; MEMBRANES; GRAPHENE;
D O I
10.1021/nn302147s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Supercapacitors (also known as ultracapacitors) are considered to be the most promising approach to meet the pressing requirements of energy storage. Supercapacitive electrode materials, which are closely related to the high-efficiency storage of energy, have provoked more interest. Herein, we present a high-capacity supercapacitor material based on the nitrogen-doped porous carbon nanofibers synthesized by carbonization of macroscopic-scale carbonaceous nanofibers (CNFs) coated with polypyrrole (CNFs@polypyrrole) at an appropriate temperature. The composite nanofibers exhibit a reversible specific capacitance of 202.0 F g(-1) at the current density of 1.0 A g(-1) in 6.0 mol L-1 aqueous KOH electrolyte, meanwhile maintaining a high-class capacitance retention capability and a maximum power density of 89.57 kW kg(-1). This kind of nitrogen-doped carbon nanofiber represents an alternative promising candidate for an efficient electrode material for supercapacitors.
引用
收藏
页码:7092 / 7102
页数:11
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