Synthesis and rheology of intercalated polystyrene/Na+-montmorillonite nanocomposites

被引：1
|
作者：
Kim, TH
Jang, LW
Lee, DC
Choi, HJ [1 ]
Jhon, MS
机构：
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
[2] Carnegie Mellon Univ, Dept Chem Engn, Pittsburgh, PA 15213 USA
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2002年 / 23卷 / 03期
关键词：
clay; emulsion polymerization; nanocomposites; polystyrene; rheology;
D O I：
10.1002/1521-3927(20020201)23:3<191::AID-MARC191>3.0.CO;2-H
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Polystyrene (PS)/clay nanocomposites were synthesized by the emulsion polymerization of styrene in the presence of sodium ion-exchanged montmorillonite (Na+-MMT), demonstrating that the strongly hydrophobic PS was intercalated into the hydrophilic silicate layers. The nanocomposites were examined by means of X-ray diffraction, transmission electron microscopy, thermogravimetric analysis. The rheological properties of the PS/Na+-MMT nanocomposites were also studied to exhibit more pronounced shear thinning behavior with increasing clay content.
引用
收藏
页码：191 / 195
页数：5
相关论文
共 50 条
  • [41] Preparation and characterization of poly(vinyl butyral)/Na+-montmorillonite nanocomposite
    Cho, CH
    Cho, MS
    Sung, JH
    Choi, HJ
    Jhon, MS
    JOURNAL OF MATERIALS SCIENCE, 2004, 39 (09) : 3151 - 3153
  • [42] Modification of Na+-montmorillonite with mono- and bis(polyfluoroalkyl) phthalates
    S. V. Kudashev
    V. F. Zheltobryukhov
    O. A. Barkovskaya
    V. M. Dronova
    K. R. Shevchenko
    Russian Journal of Applied Chemistry, 2013, 86 : 1010 - 1015
  • [43] Nanocomposites of EVA/polystyrene nanoparticles/montmorillonite
    Chuayjuljit, Saowaroj
    Worawas, Chutima
    JOURNAL OF COMPOSITE MATERIALS, 2011, 45 (06) : 631 - 638
  • [44] Melt intercalation in montmorillonite/polystyrene nanocomposites
    Nassar, N
    Utracki, LA
    Kamal, MR
    INTERNATIONAL POLYMER PROCESSING, 2005, 20 (04) : 423 - 431
  • [45] Melt Intercalation in Montmorillonite/Polystyrene Nanocomposites
    Nassar, N.
    Utracki, L. A.
    Kamal, M. R.
    INTERNATIONAL POLYMER PROCESSING, 2022, 20 (04) : 423 - 431
  • [46] Large-scale simulations of poly(propylene oxide)amine/Na+-montmorillonite and poly(propylene oxide) ammonium/Na+-montmorillonite using a molecular dynamics approach
    Boulet, P.
    Greenwell, H. C.
    Chen, B.
    Bowden, A. A.
    Beurroies, I.
    Salles, F.
    Coveney, P. V.
    Evans, J. R. G.
    Whiting, A.
    CHARACTERIZATION OF POROUS SOLIDS VII - PROCEEDINGS OF THE 7TH INTERNATIONAL SYMPOSIUM ON THE CHARACTERIZATION OF POROUS SOLIDS (COPS-VII), AIX-EN-PROVENCE, FRANCE, 26-28 MAY 2005, 2006, 160 : 311 - 318
  • [47] Preparation and characterization of poly(2-hydroxyethyl methacrylate)/Na-montmorillonite intercalated nanocomposites
    Koc, Zafer
    Celik, Meltem
    Onal, Muserref
    Sarikaya, Yuksel
    Mogulkoc, Yesim
    JOURNAL OF POLYMER ENGINEERING, 2013, 33 (01) : 27 - 32
  • [48] Synthesis and thermal properties of polystyrene/montmorillonite nanocomposites by γ-ray radiation polymerization
    Zhang, WA
    Shen, XF
    Liu, MF
    Fang, YE
    JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 90 (06) : 1692 - 1696
  • [49] Study on the synthesis and properties of polyacrylamide/Na-montmorillonite nanocomposites
    Koc, Zafer
    Celik, Meltem
    Onal, Muserref
    Sarikaya, Yuksel
    Oner, Yagmur
    Acik, Leyla
    JOURNAL OF COMPOSITE MATERIALS, 2014, 48 (04) : 439 - 446
  • [50] Synthesis of iron oxides intercalated montmorillonite and -zirconium phosphate particles and their applications in polystyrene composites
    Tan, Xiaofang
    Lu, Hongdian
    Wang, Juan
    Jin, Chen
    Yang, Wei
    Zhang, Quanzheng
    JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (44)
12345