Synthesis and rheology of intercalated polystyrene/Na+-montmorillonite nanocomposites

被引:1
作者
Kim, TH
Jang, LW
Lee, DC
Choi, HJ [1 ]
Jhon, MS
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
[2] Carnegie Mellon Univ, Dept Chem Engn, Pittsburgh, PA 15213 USA
关键词
clay; emulsion polymerization; nanocomposites; polystyrene; rheology;
D O I
10.1002/1521-3927(20020201)23:3<191::AID-MARC191>3.0.CO;2-H
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polystyrene (PS)/clay nanocomposites were synthesized by the emulsion polymerization of styrene in the presence of sodium ion-exchanged montmorillonite (Na+-MMT), demonstrating that the strongly hydrophobic PS was intercalated into the hydrophilic silicate layers. The nanocomposites were examined by means of X-ray diffraction, transmission electron microscopy, thermogravimetric analysis. The rheological properties of the PS/Na+-MMT nanocomposites were also studied to exhibit more pronounced shear thinning behavior with increasing clay content.
引用
收藏
页码:191 / 195
页数:5
相关论文
共 50 条
  • [21] Polystyrene/montmorillonite intercalation nanocomposites
    Wang, SJ
    Li, Q
    Wang, XY
    Qi, ZN
    ACTA POLYMERICA SINICA, 1998, (02) : 129 - 133
  • [22] The Tribology and Micromechanics of Polystyrene-Montmorillonite Nanocomposites
    Kotomin, S. V.
    Chang, I-Ta
    Sancaktar, E.
    Yarikov, D.
    MECHANICS OF COMPOSITE MATERIALS, 2014, 49 (06) : 651 - 658
  • [23] Synthesis and characterization of poly(glycidyl methacrylate)/Na-montmorillonite nanocomposites
    Çelik, M
    Önal, M
    JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 94 (04) : 1532 - 1538
  • [24] Properties of Nylon-6/Na+-montmorillonite nanocomposites obtained by hydrolyzed ring-opening polymerization
    Liu, Andong
    Xie, Tingxiu
    Yang, Guisheng
    MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (18) : 1572 - 1577
  • [25] Synthesis, characterization, and properties of conducting polypyrrole/Na-montmorillonite nanocomposites
    Celik, Meltem
    Onal, Muserref
    JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS, 2012, 25 (04) : 505 - 520
  • [26] Synthesis and characterization of sPS/montmorillonite nanocomposites
    Torre, L
    Lelli, G
    Kenny, JM
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 100 (06) : 4957 - 4963
  • [27] Effect of Bifunctional Montmorillonite on the Thermal and Tribological Properties of Polystyrene/Montmorillonite Nanocomposites
    Yu, Chengcheng
    Ke, Yangchuan
    Hu, Xu
    Zhao, Yi
    Deng, Qingchun
    Lu, Shichao
    POLYMERS, 2019, 11 (05)
  • [28] Synthesis of Na+-montmorillonite/amphiphilic polyurethane nanocomposite via bulk and coalescence emulsion polymerization
    Kim, JY
    Jung, WC
    Park, KY
    Suh, KD
    JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 89 (11) : 3130 - 3136
  • [29] Effects of montmorillonite and compatibilizer on the mechanical and thermal properties of dispersing intercalated PMMA nanocomposites
    Chang, Ming-Kuen
    Lee, Hsiu-Chuan
    INTERNATIONAL COMMUNICATIONS IN HEAT AND MASS TRANSFER, 2015, 67 : 21 - 28
  • [30] Comparison of Analysis Results and Modification of Na+-Montmorillonite with Ionic Liquids
    Baysal, Gulay
    Aydin, Haluk
    ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (03) : 672 - 676