An Efficient and Stable Perovskite Solar Cell with Suppressed Defects by Employing Dithizone as a Lead Indicator

被引:41
作者
Hou, Wenjing [1 ]
Han, Gaoyi [1 ]
Ou, Ting [1 ]
Xiao, Yaoming [2 ]
Chen, Qi [3 ]
机构
[1] Shanxi Univ, Inst Mol Sci, Key Lab Mat Energy Convers & Storage Shanxi Prov, State Key Lab Quantum Opt & Quantum Opt Devices, Taiyuan 030006, Peoples R China
[2] Quanzhou Normal Univ, Coll Chem Engn & Mat Sci, Quanzhou 362000, Peoples R China
[3] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
additives; dithizone; perovskites; reduced defects; solar cells;
D O I
10.1002/anie.202007353
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The defects in perovskite films are one of the most non-negligible factors that can attenuate the performances of perovskite solar cell. This work fabricates defect-reduced perovskite film by using the lead indicator (dithizone) as an additive of perovskite functional layer. The dithizone can retard the crystallization rate of perovskite films, passivate the defects, and enhance the structure stability of perovskite by coordinating with lead atoms. As a result, the device doped with dithizone yields outstanding power conversion efficiency and stability.
引用
收藏
页码:21409 / 21413
页数:5
相关论文
共 30 条
  • [1] Highly efficient ultrasonic-assisted pre-concentration and simultaneous determination of trace amounts of Pb (II) and Cd (II) ions using modified magnetic natural clinoptilolite zeolite: Response surface methodology
    Amiri-Yazani, T.
    Zare-Dorabei, R.
    Rabbani, M.
    Mollahosseini, A.
    [J]. MICROCHEMICAL JOURNAL, 2019, 146 : 498 - 508
  • [2] Ball JM, 2016, NAT ENERGY, V1, P1, DOI [10.1038/NENERGY.2016.149, 10.1038/nenergy.2016.149]
  • [3] Bi DQ, 2016, NAT ENERGY, V1, DOI [10.1038/nenergy.2016.142, 10.1038/NENERGY.2016.142]
  • [4] A solvent- and vacuum-free route to large-area perovskite films for efficient solar modules
    Chen, Han
    Ye, Fei
    Tang, Wentao
    He, Jinjin
    Yin, Maoshu
    Wang, Yanbo
    Xie, Fengxian
    Bi, Enbing
    Yang, Xudong
    Gratzel, Michael
    Han, Liyuan
    [J]. NATURE, 2017, 550 (7674) : 92 - +
  • [5] Impacts of alkaline on the defects property and crystallization kinetics in perovskite solar cells
    Chen, Yihua
    Li, Nengxu
    Wang, Ligang
    Li, Liang
    Xu, Ziqi
    Jiao, Haoyang
    Liu, Pengfei
    Zhu, Cheng
    Zai, Huachao
    Sun, Mingzi
    Zou, Wei
    Zhang, Shuai
    Xing, Guichuan
    Liu, Xinfeng
    Wang, Jianpu
    Li, Dongdong
    Huang, Bolong
    Chen, Qi
    Zhou, Huanping
    [J]. NATURE COMMUNICATIONS, 2019, 10 (1)
  • [6] Impact of microstructure on local carrier lifetime in perovskite solar cells
    deQuilettes, Dane W.
    Vorpahl, Sarah M.
    Stranks, Samuel D.
    Nagaoka, Hirokazu
    Eperon, Giles E.
    Ziffer, Mark E.
    Snaith, Henry J.
    Ginger, David S.
    [J]. SCIENCE, 2015, 348 (6235) : 683 - 686
  • [7] Alkyl-Chain-Regulated Charge Transfer in Fluorescent Inorganic CsPbBr3 Perovskite Solar Cells
    Duan, Jialong
    Wang, Yudi
    Yang, Xiya
    Tang, Qunwei
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (11) : 4391 - 4395
  • [8] Chlorine-Incorporation-Induced Formation of the Layered Phase for Antimony-Based Lead-Free Perovskite Solar Cells
    Jiang, Fangyuan
    Yang, Dongwen
    Jiang, Youyu
    Liu, Tiefeng
    Zhao, Xingang
    Ming, Yue
    Luo, Bangwu
    Qin, Fei
    Fan, Jiacheng
    Han, Hongwei
    Zhang, Lijun
    Zhou, Yinhua
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (03) : 1019 - 1027
  • [9] Nickel Ferrite Magnetic Nanoparticles as a Sorbent for Solid Phase Extraction of Trace Lead from Water Prior to Spectrophotometric Determination
    Khoshhesab, Z. Monsef
    Divsar, F.
    [J]. JOURNAL OF ANALYTICAL CHEMISTRY, 2019, 74 (04) : 316 - 322
  • [10] Cation and anion immobilization through chemical bonding enhancement with fluorides for stable halide perovskite solar cells
    Li, Nengxu
    Tao, Shuxia
    Chen, Yihua
    Niu, Xiuxiu
    Onwudinanti, Chidozie K.
    Hu, Chen
    Qiu, Zhiwen
    Xu, Ziqi
    Zheng, Guanhaojie
    Wang, Ligang
    Zhang, Yu
    Li, Liang
    Liu, Huifen
    Lun, Yingzhuo
    Hong, Jiawang
    Wang, Xueyun
    Liu, Yuquan
    Xie, Haipeng
    Gao, Yongli
    Bai, Yang
    Yang, Shihe
    Brocks, Geert
    Chen, Qi
    Zhou, Huanping
    [J]. NATURE ENERGY, 2019, 4 (05) : 408 - 415