Tri-Diketopyrrolopyrrole Molecular Donor Materials for High-Performance Solution-Processed Bulk Heterojunction Solar Cells

被引:101
作者
Liu, Jianhua [1 ]
Sun, Yanming [2 ]
Moonsin, Preecha [3 ,4 ]
Kuik, Martijn [1 ]
Proctor, Christopher M. [1 ]
Lin, Jason [1 ]
Hsu, Ben B. [2 ]
Promarak, Vinich [3 ,4 ]
Heeger, Alan J. [2 ]
Thuc-Quyen Nguyen [1 ]
机构
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Phys, Ctr Polymers & Organ Solids, Santa Barbara, CA 93106 USA
[3] Suranaree Univ Technol, Inst Sci, Sch Chem, Nakhon Ratchasima 30000, Thailand
[4] Suranaree Univ Technol, Inst Sci, Ctr Excellence Innovat Chem, Nakhon Ratchasima 30000, Thailand
基金
美国国家科学基金会;
关键词
organic photovoltaics; bulk heterojunction; molecular donor; diketopyrrolopyrrole; ENERGY-LEVELS; SEMICONDUCTORS; MORPHOLOGY;
D O I
10.1002/adma.201302007
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two new high-performance DPP-containing donor molecules employing a molecular architecture with three DPP chromorphores (tri-DPP) in conjugated backbones are synthesized and characterized. The two tri-DPP molecules with only a structural difference on alkyl substitutions, when blended with PC 71BM, lead to power conversion efficiencies up to 4.8 and 5.5%, respectively. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5898 / 5903
页数:6
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