Manufacturing and performance assessment of stamped, laser welded, and nitrided FeCrV stainless steel bipolar plates for proton exchange membrane fuel cells

被引:31
作者
Brady, M. P. [1 ]
Abd Elhamid, M. [2 ]
Dadheech, G. [2 ]
Bradley, J. [2 ]
Toops, T. J. [1 ]
Meyer, H. M., III [1 ]
Tortorelli, P. F. [1 ]
机构
[1] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA
[2] Gen Motors Tech Ctr, Warren, MI 48090 USA
基金
美国能源部;
关键词
Proton exchange membrane fuel cell (PEMFC); Bipolar plate; Stainless steel; Nitride; Nitridation; Corrosion; ALLOY FOIL;
D O I
10.1016/j.ijhydene.2013.01.143
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A manufacturing and single-cell fuel cell performance study of stamped, laser welded, and gas nitrided ferritic stainless steel foils in an advanced automotive bipolar plate assembly design was performed. Two developmental foil compositions were studied: Fe-20Cr-4V and Fe-23Cr-4V wt.%. Foils 0.1 mm thick were stamped and then laser welded together to create single bipolar plate assemblies with cooling channels. The plates were then surface treated by pre-oxidation and nitridation in N-2-4H(2) based gas mixtures using either a conventional furnace or a short-cycle quartz lamp infrared heating system. Single-cell fuel cell testing was performed at 80 degrees C for 500 h at 0.3 A/cm(2) using 100% humidification and a 100%/40% humidification cycle that stresses the membrane and enhances release of the fluoride ion and promotes a more corrosive environment for the bipolar plates. Periodic high frequency resistance potential-current scans during the 500 h fuel cell test and post-test analysis of the membrane indicated no resistance increase of the plates and only trace levels of metal ion contamination. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:4734 / 4739
页数:6
相关论文
共 11 条
[1]   The formation of protective nitride surfaces for PEM fuel cell metallic bipolar plates [J].
Brady, M. P. ;
Yang, B. ;
Wang, H. ;
Turner, J. A. ;
More, K. L. ;
Wilson, M. ;
Garzon, F. .
JOM, 2006, 58 (08) :50-57
[2]   Pre-oxidized and nitrided stainless steel alloy foil for proton exchange membrane fuel cell bipolar plates: Part 1. Corrosion, interfacial contact resistance, and surface structure [J].
Brady, M. P. ;
Wang, H. ;
Turner, J. A. ;
Meyer, H. M., III ;
More, K. L. ;
Tortorelli, P. F. ;
McCarthy, B. D. .
JOURNAL OF POWER SOURCES, 2010, 195 (17) :5610-5618
[3]   Effects of thermal oxi-nitridation on the corrosion resistance and electrical conductivity of 446M stainless steel for PEMFC bipolar plates [J].
Lee, Ki-Hyoung ;
Lee, Seok-Hyun ;
Kim, Jong-Hee ;
Lee, Yun-Yong ;
Kim, Young-Hwan ;
Kim, Min-Chul ;
Wee, Dang-Moon .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (03) :1515-1521
[4]   Corrosion behavior of pre-oxidized and thermally nitrided stainless steel for polymer electrolyte membrane fuel cell bipolar plates [J].
Lee, Seok-Hee ;
Yang, Tae-Hyun ;
Hyun, Sang-Hoon ;
Yoon, Young-Soo .
CORROSION SCIENCE, 2012, 58 :79-85
[5]   Materials selection for bipolar plates for polymer electrolyte membrane fuel cells using the Ashby approach [J].
Lopes de Oliveira, Mara Cristina ;
Ett, Gerhard ;
Antunes, Renato Altobelli .
JOURNAL OF POWER SOURCES, 2012, 206 :3-13
[6]   In situ metal ion contamination and the effects on proton exchange membrane fuel cell performance [J].
Sulek, Mark ;
Adams, Jim ;
Kaberline, Steve ;
Ricketts, Mark ;
Waldecker, James R. .
JOURNAL OF POWER SOURCES, 2011, 196 (21) :8967-8972
[7]   Metal bipolar plates for PEM fuel cell - A review [J].
Tawfik, H. ;
Hung, Y. ;
Mahajan, D. .
JOURNAL OF POWER SOURCES, 2007, 163 (02) :755-767
[8]   Pre-oxidized and nitrided stainless steel alloy foil for proton exchange membrane fuel cell bipolar plates. Part 2: Single-cell fuel cell evaluation of stamped plates [J].
Toops, Todd J. ;
Brady, Michael P. ;
Tortorelli, Peter F. ;
Pihl, Josh A. ;
Estevez, Francisco ;
Connors, Daniel ;
Garzon, Fernando ;
Rockward, Tommy ;
Gervasio, Don ;
Mylan, William ;
Kosaraju, Sree Harsha .
JOURNAL OF POWER SOURCES, 2010, 195 (17) :5619-5627
[9]   Reviewing Metallic PEMFC Bipolar Plates [J].
Wang, H. ;
Turner, J. A. .
FUEL CELLS, 2010, 10 (04) :510-519
[10]   The influence of metal ions on the conductivity of Nafion 112 in polymer electrolyte membrane fuel cell [J].
Wang, Heli ;
Turner, John A. .
JOURNAL OF POWER SOURCES, 2008, 183 (02) :576-580