Self-organized chemical nanoscale microreactors

被引:41
作者
Hildebrand, M
Kuperman, M
Wio, H
Mikhailov, AS
Ertl, G
机构
[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
[2] Ctr Atom Bariloche, RA-8400 Bariloche, Rio Negro, Argentina
[3] Consejo Nacl Invest Cient & Tecn, Inst Balseiro, RA-8400 Bariloche, Rio Negro, Argentina
关键词
D O I
10.1103/PhysRevLett.83.1475
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Nonequilibrium localized structures of submicrometer and nanometer sizes, carrying the reaction, can spontaneously develop under reaction conditions on a catalytic surface. These self-organized microreactors emerge because of the coupling between the reaction and a structural phase transition in the substrate. The corresponding localized solutions are constructed using the singular perturbation approximation and reproduced in numerical simulations.
引用
收藏
页码:1475 / 1478
页数:4
相关论文
共 50 条
[41]   Self-Organized Stationary Patterns in Networks of Bistable Chemical Reactions [J].
Kouvaris, Nikos E. ;
Sebek, Michael ;
Mikhailov, Alexander S. ;
Kiss, Istvan Z. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (42) :13267-13270
[42]   Chemical reactivity of self-organized alumina nanopores in aqueous medium [J].
Rocca, E. ;
Vantelon, D. ;
Gehin, A. ;
Augros, M. ;
Viola, A. .
ACTA MATERIALIA, 2011, 59 (03) :962-970
[43]   FIXATION OF SELF-ORGANIZED CHEMICAL WAVE PATTERNS ON COTTON CLOTH [J].
SHIBUYA, TI ;
NISHIKAWA, A .
TEXTILE RESEARCH JOURNAL, 1982, 52 (06) :419-420
[44]   Self-Organized Resonance during Search of a Diverse Chemical Space [J].
Kachman, Tal ;
Owen, Jeremy A. ;
England, Jeremy L. .
PHYSICAL REVIEW LETTERS, 2017, 119 (03)
[45]   SELF-ORGANIZED CHEMICAL-MODEL AND THE APPLICATION TO MEMBRANE EXCITATION [J].
TOKIMOTO, T ;
SHIRANE, K .
PHYSICS LETTERS A, 1989, 137 (7-8) :373-378
[46]   THE STUDY OF THE EVOLUTION OF SOME SELF-ORGANIZED CHEMICAL-SYSTEMS [J].
BOURCEANU, G ;
MOROSANU, G .
JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (08) :3685-3691
[47]   Nanoscale to macroscale investigation of the frictional properties of physisorbed layers of self-organized phthalocyanine derivatives [J].
Miyake, K. ;
Nakano, M. ;
Korenaga, A. ;
Hori, Y. ;
Ikeda, T. ;
Asakawa, M. ;
Shimizu, T. ;
Sasaki, S. ;
Ando, Y. .
TRIBOLOGY LETTERS, 2008, 31 (01) :9-15
[48]   Optical spectroscopy of self-organized nanoscale heterostructures involving high-index surfaces [J].
Ledentsov, NN ;
Maximov, MV ;
Kopev, PS ;
Ustinov, VM ;
Belousov, MV ;
Meltser, BY ;
Ivanov, SV ;
Shchukin, VA ;
Alferov, ZL ;
Grundmann, M ;
Bimberg, D ;
Ruvimov, SS ;
Richter, W ;
Werner, P ;
Gosele, U ;
Heidenreich, J ;
Wang, PD ;
Torres, CMS .
MICROELECTRONICS JOURNAL, 1995, 26 (08) :871-879
[49]   Nanoscale Anatomy of Iron-Silica Self-Organized Membranes: Implications for Prebiotic Chemistry [J].
Kotopoulou, Electra ;
Lopez-Haro, Miguel ;
Calvino Gamez, Jose Juan ;
Garcia-Ruiz, Juan Manuel .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (03) :1396-1402
[50]   Nanoscale to Macroscale Investigation of the Frictional Properties of Physisorbed Layers of Self-Organized Phthalocyanine Derivatives [J].
K. Miyake ;
M. Nakano ;
A. Korenaga ;
Y. Hori ;
T. Ikeda ;
M. Asakawa ;
T. Shimizu ;
S. Sasaki ;
Y. Ando .
Tribology Letters, 2008, 31 :9-15