Novel solid acid catalyst for the production of 5-hydroxymethylfurfural with fructose dehydration

被引：4

作者：

Liu, Sile ^{[1
]}

Shang, Dongmei ^{[1
]}

Wang, Hailong ^{[1
]}

Wu, Jing ^{[1
,2
]}

机构：

[1] Shenyang Inst Sci & Technol, Shenyang, Peoples R China

[2] Shenyang Univ Chem Technol, Shenyang, Peoples R China

来源：

BIO-MEDICAL MATERIALS AND ENGINEERING | 2022年 / 33卷 / 06期

关键词：

Phosphotungstic acid; catalyst; fructose; 5-Hydroxymethylfurfural; 2,5-FURANDICARBOXYLIC ACID; NIOBIUM PHOSPHATE; CONVERSION; EFFICIENT; GLUCOSE; BIOMASS; PERFORMANCE; OXIDATION;

D O I：

10.3233/BME-211385

中图分类号：

R318 [生物医学工程];

学科分类号：

0831 ;

摘要：

BACKGROUND: 5-Hydroxymethylfurfural (5-HMF) is a high value-added platform compound which can be obtained by dehydration of hexose under acidic conditions. OBJECTIVE: In this paper, a novel impregnation strategy for the molecular sieves (ZSM-5) as carrier and phosphotungstic acid (TPA) as active ingredient is proposed, the influence of the fructose dehydration process were studied and eco-friendliness, low-cost 5-hydroxymethylfurfural (5-HMF) was successfully obtained. METHOD: The structure surface area, pore size, acidity and microstructure of solid acid catalysts were investigated by XRD, BET, NH3-TPD and SEM. The influences of reaction temperature, reaction time, catalyst dosage on the yield of 5-hydroxymethylfurfural (5-HFM) were investigated. RESULTS: The results showed that TPA/ZSM-5 (mass ratio 20:10) has good dispersion and catalytic activity, fructose dosage 5 g, reaction temperature 140 degrees C, reaction time 2 h, catalyst dosage 0.5 g, and the yield of 5-hydroxymethylfurfural was 80.75% and after five times use the yield of 5-HMF remained above 75%. CONCLUSION: The novel solid acid TPA/ZSM-5 catalyst exhibited good catalytic activity and stability for the fructose dehydration to produce 5-HMF.

引用

页码：477 / 489

页数：13

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