Predictions for the Sound Velocity in Various Liquid Metals at Their Melting Point Temperatures

被引:10
作者
Iida, Takamichi [1 ]
Guthrie, Roderick [2 ]
机构
[1] Osaka Univ, Suita, Osaka 5650871, Japan
[2] McGill Univ, McGill Met Proc Ctr, Montreal, PQ H3A 2B2, Canada
来源
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE | 2009年 / 40卷 / 06期
关键词
THERMOPHYSICAL PROPERTY MEASUREMENTS; SURFACE-TENSION; ACCURATE PREDICTIONS; VISCOSITY; TRANSPORT;
D O I
10.1007/s11663-009-9299-y
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sound velocity values for 32 liquid metals at their melting point temperatures have been predicted using two models that we presented; most of these metals are transition and rare earth metals. The sound velocities for most of these liquid metals have yet to be measured experimentally. Dimensionless common parameters, denoted by xi(1/2)(T) and xi(1/2)(E), were determined on the basis of the predicted sound velocities. These common parameters, which characterize the liquid state (i.e., an atom's hardness or softness and its anharmonic motions), allow for better predictions of several thermophysical properties (e.g., surface tension, viscosity, self-diffusivity, volume expansivity) of liquid metallic elements. The values of both the common parameters xi(1/2)(T) and xi(1/2)(E) vary periodically with atomic number. Using our viscosity model in terms of the parameter xi(1/2)(T), values of melting point viscosity were calculated for liquid molybdenum and platinum. The agreement obtained between calculated and experimental values is good when using predicted values of xi(1/2)(T) to calculate their viscosities.
引用
收藏
页码:959 / 966
页数:8
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