RETRACTED: Tris(ethylenediamine)manganese(II) sulfate (Retracted Article)

被引:2
作者
Lu, Jing [1 ]
机构
[1] Liaocheng Univ, Sch Chem & Chem Engn, Liaocheng 252059, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2009年 / 65卷
基金
中国国家自然科学基金;
关键词
D O I
10.1107/S1600536809034874
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Mn(C2H8N2)(3)]SO4, the metal atom (site symmetry 3.2) is coordinated by six N atoms from three ethylenediamine (en) ligands in a slightly distorted octahedral geometry. The en ligands are generated from one half-molecule in the asymmetric unit. The O atoms of the sulfate anion (S site symmetry 3.2) are disordered over four orientations in a 0.220 (12): 0.210 (13): 0.203 (14): 0.10 (2) ratio, with one of the O atoms having site symmetry 3. In the crystal, the ions are connected by N-H center dot center dot center dot O hydrogen bonds, forming a three-dimensional network.
引用
收藏
页码:M1187 / +
页数:8
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