A porous Cu(II) metal-organic framework: Synthesis, crystal structure and gas adsorption properties

被引：10
作者：
Li, Wu-Wu [1 ]
Guo, Ying [1 ]
Zhang, Wei-Hong [1 ]
机构：
[1] Xianyang Normal Univ, Coll Chem & Chem Engn, Xianyang 712000, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2017年 / 1143卷
关键词：
Solvothermal reactions; Cu(II) compound; Gas adsorption; Light hydrocarbons; HIGHLY SELECTIVE SORPTION; LIGAND; CAPACITY; CO2; HYDROCARBONS; ACETYLENE; UNITS;
D O I：
10.1016/j.molstruc.2017.04.068
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Presented here is a new porous Cu(II) metal-organic framework, namely [Cu(tdc)(H2O)](n)center dot n(DMA) (1 H(2)tdc = thiophene-2,5-dicarboxylic acid, DMA = N,N'-dimethylacetamide), which was obtained by the self-assembly reaction of CuCl2 and H(2)tdc under solvothermal conditions. Single crystal X-ray diffraction analysis revealed that compound 1 features a 3D porous framework based on ID chain structure sub-units, and the 1D rhombohedral channels are occupied by the lattice DMA molecules. Gas adsorption studies reveal that this desolvated sample exhibit high uptake capacity for light hydrocarbons. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：20 / 22
页数：3
相关论文
共 22 条
  • [1] [Anonymous], 1997, SHELXTL 97 PROGRAM R
  • [2] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture
    Banerjee, Rahul
    Phan, Anh
    Wang, Bo
    Knobler, Carolyn
    Furukawa, Hiroyasu
    O'Keeffe, Michael
    Yaghi, Omar M.
    [J]. SCIENCE, 2008, 319 (5865) : 939 - 943
  • [3] A New Approach to Construct a Doubly Interpenetrated Microporous Metal-Organic Framework of Primitive Cubic Net for Highly Selective Sorption of Small Hydrocarbon Molecules
    Das, Madhab C.
    Xu, Hui
    Xiang, Shengchang
    Zhang, Zhangjing
    Arman, Hadi D.
    Qian, Guodong
    Chen, Banglin
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (28) : 7817 - 7822
  • [4] Highly Selective Sorption of Small Hydrocarbons and Photocatalytic Properties of Three Metal-Organic Frameworks Based on Tris(4-(1H-imidazol-1-yl)phenyl)amine Ligand
    Fu, Hong-Ru
    Kang, Yao
    Zhang, Jian
    [J]. INORGANIC CHEMISTRY, 2014, 53 (08) : 4209 - 4214
  • [5] Photophysical Studies of Europium Coordination Polymers Based on a Tetracarboxylate Ligand
    Gai, Yan-Li
    Jiang, Fei-Long
    Chen, Lian
    Bu, Yang
    Su, Kong-Zhao
    Al-Thabaiti, Shaeel A.
    Hong, Mao-Chun
    [J]. INORGANIC CHEMISTRY, 2013, 52 (13) : 7658 - 7665
  • [6] A 3D chiral nanoporous coordination framework consisting of homochiral nanotubes assembled from octuple helices
    Hao, Xiang-Rong
    Wang, Xin-Long
    Qin, Chao
    Su, Zhong-Min
    Wang, En-Bo
    Lan, Ya-Qian
    Shao, Kui-Zhan
    [J]. CHEMICAL COMMUNICATIONS, 2007, (44) : 4620 - 4622
  • [7] A highly robust metal-organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4
    He, Hongming
    Song, Yang
    Zhang, Chuanqi
    Sun, Fuxing
    Yuan, Rongrong
    Bian, Zheng
    Gao, Lianxun
    Zhu, Guangshan
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (46) : 9463 - 9466
  • [8] Synthesis of metal-adeninate frameworks with high separation capacity on C2/C1 hydrocarbons
    He, Yan-Ping
    Zhou, Nan
    Tan, Yan-Xi
    Wang, Fei
    Zhang, Jian
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2016, 238 : 241 - 245
  • [9] Gas Sorption, Second-Order Nonlinear Optics, and Luminescence Properties of a Series of Lanthanide-Organic Frameworks Based on Nanosized Tris((4-carboxyl)phenylduryl)amine Ligand
    He, Yan-Ping
    Tan, Yan-Xi
    Zhang, Jian
    [J]. INORGANIC CHEMISTRY, 2013, 52 (21) : 12758 - 12762
  • [10] Wings waving: coordinating solvent- induced structural diversity of new Cu(II) flexible MOFs with crystal to crystal transformation and gas sorption capability
    Ju, Zhanfeng
    Yuan, Daqiang
    [J]. CRYSTENGCOMM, 2013, 15 (45): : 9513 - 9520
123