Pentannulation of Heterocycles by Virtue of Precious Metal Catalysis

被引：18

作者：

Petrovic, Martina ^{[1
]}

Occhiato, Ernesto G. ^{[1
]}

机构：

[1] Univ Florence, Dept Chem U Schiff, Via Lastruccia 13, I-50019 Sesto Fiorentino, Italy

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 05期

关键词：

heterocycles; natural products; pentannulation; precious metals; tandem reactions; DIELS-ALDER REACTION; ONE-POT SYNTHESIS; NAZAROV CYCLIZATION; RH(I)-CATALYZED CYCLOCARBONYLATION; DIAZABICYCLIC ALKENES; PROPARGYLIC ESTERS; GOLD; CYCLOISOMERIZATION; CYCLOPENTENONES; DERIVATIVES;

D O I：

10.1002/asia.201501127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pentannulated heterocycles are the key structural subunit of many natural and biologically active compounds. Over the last decades, many precious metal-assisted pentannulations have been described as a consequence of an extensive research. This Focus Review gives an overview of precious metal-catalyzed reactions applied to the synthesis of cyclopenta-fused heterocycles in the last five years.

引用

页码：642 / 659

页数：18

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