A Structurally Characterized Organometallic Plutonium(IV) Complex

被引：27

作者：

Apostolidis, Christos ^{[1
]}

Walter, Olaf ^{[1
]}

Vogt, Jochen ^{[2
]}

Liebing, Phil ^{[2
]}

Maron, Laurent ^{[3
]}

Edelmann, Frank T. ^{[2
]}

机构：

[1] European Commiss, Joint Res Ctr, Directorate Nucl Safety & Secur G, POB 2340, D-76125 Karlsruhe, Germany

[2] Otto von Guericke Univ, Inst Chem, Univ Pl 2, D-39106 Magdeburg, Germany

[3] Univ Toulouse, INSA, CNRS, Lab Phys & Chim Nanoobjets LPCNO,UMR5215, 135 Ave Rangueil, F-31077 Toulouse 4, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2017年 / 56卷 / 18期

关键词：

plutonium; sandwich complexes; silyl group migration; X-ray crystallography; TRIS(ETA-5-CYCLOPENTADIENYL) ACTINIDE COMPLEXES; FOCK PERTURBATION-THEORY; BUILDING-BLOCK APPROACH; F-ORBITAL COVALENCY; SANDWICH COMPLEXES; ELECTRONIC-STRUCTURE; CRYSTAL-STRUCTURE; CYCLOOCTATETRAENYL COMPLEXES; TH-PU; ACTINOCENES;

D O I：

10.1002/anie.201701858

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The blood-red plutonocene complex Pu(1,3-COT '')(1,4-COT '') (4; COT '' = eta(8)-bis(trimethylsilyl) cyclooctatetraenyl) has been synthesized by oxidation of the anionic sandwich complex Li[Pu(1,4-COT '')(2)] (3) with anhydrous cobalt(II) chloride. The first crystal structure determination of an organoplutonium(IV) complex revealed an asymmetric sandwich structure for 4 where one COT '' ring is 1,3-substituted while the other retains the original 1,4-substitution pattern. The electronic structure of 4 has been elucidated by a computational study, revealing a probable cause for the unexpected silyl group migration.

引用

页码：5066 / 5070

页数：5

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