Distinct activation of Cu-MOR for direct oxidation of methane to methanol

被引：86

作者：

Kim, Younhwa ^{[1
,2
]}

Kim, Tae Yong ^{[1
,2
]}

Lee, Hyunjoo ^{[3
]}

Yi, Jongheop ^{[1
,2
]}

机构：

[1] Seoul Natl Univ, Sch Chem & Biol Engn, Seoul 151742, South Korea

[2] Seoul Natl Univ, Inst Chem Proc, World Class Univ, Program Chem Convergence Energy & Environm C2E2, Seoul 151742, South Korea

[3] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Daejeon 305701, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 29期

基金：

新加坡国家研究基金会;

关键词：

LOW-TEMPERATURE; ACTIVE-SITES; COPPER; ZEOLITES; CU-ZSM-5; CONVERSION; MORDENITE; ZSM-5; STABILITY; CLUSTERS;

D O I：

10.1039/c7cc00467b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N2O activation of Cu-MOR enhanced methanol production at elevated temperatures, to a greater extent than activation by O-2 under optimal conditions. The increase in methanol production by N2O activation was attributed to the facile formation of an active copper center with no formation of inactive intermediate species.

引用

页码：4116 / 4119

页数：4

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