Acoustical and excess thermodynamic studies of molecular interaction in aqueous mixed solvent systems at 303, 308 and 313 K

被引：20

作者：

Palani, R. ^{[1
]}

Geetha, A. ^{[1
]}

机构：

[1] Annamalai Univ, Dept Phys, DDE, Annamalainagar 608002, Tamil Nadu, India

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2009年 / 47卷 / 05期

关键词：

ultrasonic velocity; excess thermodynamic parameters; interaction parameter; hydrogen bonding; BINARY-LIQUID MIXTURES; MOLAR VOLUMES; REFRACTIVE-INDEX; PLUS WATER; VISCOSITIES; 1,4-DIOXANE; N; N-DIMETHYLFORMAMIDE; DIMETHYLSULFOXIDE; TETRAHYDROFURAN; CYCLOHEXANE;

D O I：

10.1080/00319100802562862

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ultrasonic velocity (U), density (rho) and viscosity (eta) for the ternary liquid mixtures of water + propylene glycol + tetrahydrofuran, water + propylene glycol + dimethylformamide, water + propylene glycol + dimethylsulphoxide and water + propylene glycol + 1,4-dioxane have been measured as a function of the composition at 303, 308 and 313 K. The experimental data have been used to calculate some excess thermodynamical parameters such as excess viscosity (eta(E)), excess free volume (V(f)(E)), excess Gibb's free energy (Delta G(E)) and interaction parameter (d). The results are discussed and interpreted in terms of structural and specific interaction predominated by hydrogen bonding.

引用

页码：542 / 552

页数：11

共 24 条

[1] Excess thermodynamic properties of ternary liquid mixtures of xylenes with butyl acrylate and methyl methacrylate solvents at 303, 308 and 313 K
Palani, R.
Saravanan, S.
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2011, 88 (02) : 205 - 210
[2] Intermolecular Interaction Studies of Brompheniramine with 1-Propanol at 303 K, 308 K and 313 K
Sampandam, Elangovan
Garbi, Tilahun Diriba
Abbo, Yilak Alemu
CHEMISTRY AFRICA-A JOURNAL OF THE TUNISIAN CHEMICAL SOCIETY, 2020, 3 (04): : 1101 - 1107
[3] Excess thermodynamic and acoustic properties for the binary mixtures of Methyl Benzoate at T = (303, 308, 313, 318 and 323) K
Sastry, S. Sreehari
Shaik, Babu
Vishwam, T.
Ha, Sie Tiong
PHYSICS AND CHEMISTRY OF LIQUIDS, 2014, 52 (02) : 272 - 286
[4] Speed of sound and associated acoustical parameters of Schiff base solutions at 303, 308 and 313 K
Gangani, B. J.
Parsania, P. H.
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2015, 92 (07) : 1097 - 1103
[5] Acoustic and Excess Thermodynamic Properties of Higher Alcohol with Alkylamine in Cycloalkane Medium at 303 K, 308 K
Vijay Alexander, M.
Meenakshi, G.
CHEMISTRY AFRICA-A JOURNAL OF THE TUNISIAN CHEMICAL SOCIETY, 2021, 4 (04): : 881 - 894
[6] Thermophysical Studies of Chlorpheniramine with 1-Propanol at 303 K, 308 K, and 313 K in the Atmospheric Pressure
Elangovan, Sampandam
JOURNAL OF CHEMISTRY, 2022, 2022
[7] Thermodynamic properties of binary mixtures of 1,3,4-oxadiazole derivative with chloroform, N, N-dimethyl formamide at 303, 308 and 313 K and atmospheric pressure
Godhani, Dinesh R.
Dobariya, Purvesh B.
Sanghani, Anil M.
Mehta, Jignasu P.
ARABIAN JOURNAL OF CHEMISTRY, 2017, 10 : S422 - S430
[8] Acoustical Studies on Molecular Interactions in Binary Liquid Mixtures at 303 K
Uvarani, R.
Sivapragasam, J.
E-JOURNAL OF CHEMISTRY, 2009, 6 (04) : 1150 - 1152
[9] Acoustical and excess thermodynamic studies of ternary liquid mixtures of some primary alkanols in mixed binary solvent at varying temperatures
Thirumaran, S.
Priya, D.
INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 2013, 51 (06) : 413 - 420
[10] Molecular interaction of aspartic acid in aqueous metal chloride solution - Volumetric, viscometric, acoustical and optical studies
Umaley, K. D.
Aswar, A. S.
INDIAN JOURNAL OF CHEMICAL TECHNOLOGY, 2012, 19 (04) : 295 - 302

← 1 2 3 →