Gas phase spectroscopy of the pentapeptide FDASV

被引：36
作者：
Abo-Riziq, Ali [1 ]
Bushnell, John E. [1 ]
Crews, Bridgit [1 ]
Callahan, Michael [1 ]
Grace, Louis [1 ]
De Vries, Mattanjah S. [1 ]
机构：
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
来源：
CHEMICAL PHYSICS LETTERS | 2006年 / 431卷 / 4-6期
关键词：
D O I：
10.1016/j.cplett.2006.09.103
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
IR-UV double resonance spectroscopy of the laser-desorbed, jet-cooled pentapeptide FDASV shows only one type of conformer in the gas phase. Comparison with computations at the B3LYP/6-31G** level suggests formation of an alpha-turn in the absence of solvent stabilization. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：227 / 230
页数：4
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