Synthesis of biaryl-styrene monomers by microwave-assisted Suzuki coupling

被引：13
|
作者：
Zayas, Hazit A. [1 ]
Bowyer, Michael C. [1 ]
Gordon, Christopher P. [1 ]
Holdsworth, Clovia I. [1 ]
McCluskey, Adam [1 ]
机构：
[1] Univ Newcastle, Sch Environm & Life Sci, Callaghan, NSW 2308, Australia
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 43期
基金：
英国医学研究理事会; 澳大利亚研究理事会;
关键词：
Suzuki coupling; Microwave-assisted synthesis; Styrenic monomers; 4-Vinylboronic acid; POLYMERS;
D O I：
10.1016/j.tetlet.2009.07.117
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Biaryl-styrenic monomers are prepared via Suzuki coupling as functional monomers in the synthesis of molecularly imprinted polymers. Traditional thermal Suzuki approaches are hampered by competition between Suzuki, Heck and homo-coupling reactions. Microwave-assisted approaches facilitated rapid access to the desired Suzuki products whilst suppressing both Heck and homo-couplings of 4-vinylboronic acid. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：5894 / 5895
页数：2
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