Synthesis and Crystal Structure of a New 3D-Supramolecular Complex: [Cd(C10H12N2O)2I2(H2O)2]

被引：0

作者：

Yao, Ru-Fu ^{[1
]}

Bi, Jian-Hong ^{[1
]}

机构：

[1] Hefei Teachers Coll, Dept Chem & Chem Engn, Hefei 230061, Peoples R China

来源：

ASIAN JOURNAL OF CHEMISTRY | 2009年 / 21卷 / 08期

关键词：

Cadmium(II) complex; Crystal structure; Hydrogen bonds; Superamolecular; CDI2; CRYSTALS; PHOTOLUMINESCENCE; CHAIN;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel complex [Cd(C10H12N2O)(2)I-2(H2O)(2)], was synthesized and characterized by IR spectra. elemental analysis and single-crystal X-ray. The crystal structure analysis shows that the Cd(II) is a six-coordinated in a slightly distorted octahedral geometry environment, then complex packs in 3D-superamolecular network through intermolecular hydrogen bonds. The crystal is monoclinic, space group C2/c with unit cell parameters: a = 21.861(2)angstrom, b = 8.642(8)angstrom, c = 14.732(2)angstrom, alpha = 90 degrees, beta = 114.4(1)degrees, gamma = 90 degrees, V = 2534.1(4)angstrom(3), Z = 4, Mr = 754.7, Dc = 1.978 Mg/cm(3), mu = 3.330 mm(-1). F(000) = 1448, T = 291(2) K, R = 0.0472, wR = 0.1235 for 2484 reflections with I > 2 sigma(I).

引用

页码：6445 / 6448

页数：4

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