Synthesis and catalytic properties of novel ruthenium N-heterocyclic-carbene complexes

被引：30

作者：

Demir, Serpil ^{[1
]}

Ozdemir, Ismail ^{[1
]}

Cetinkaya, Bekir ^{[2
]}

机构：

[1] Inonu Univ, Fac Sci & Art, Dept Chem, TR-44280 Malatya, Turkey

[2] Ege Univ, Fac Sci, Dept Chem, TR-35100 Bornova, Turkey

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2009年 / 694卷 / 25期

关键词：

Ruthenium; Imidazolinium salts; N-heterocyclic carbene; C-H bond activation; Arylation; H BOND FUNCTIONALIZATION; DIRECT ORTHO ARYLATION; TEMPLATE SYNTHESIS; COUPLING REACTIONS; GOLD(I) COMPLEXES; ORGANOMETALLIC CHEMISTRY; COORDINATION CHEMISTRY; (NHC)PD(ALLYL)CL NHC; PALLADIUM COMPLEXES; ALKENE METATHESIS;

D O I：

10.1016/j.jorganchem.2009.08.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [RuCl2(p-cymene)](2) with 1,3-dialkylimidazolinium salts 1a-f in the presence of a small excess of cesium carbonate yields chelated eta(6)-arene, eta(1)-carbene ruthenium complexes 2a-f. All synthesised compounds were characterized by elemental analysis, NMR spectroscopy. The catalytic activity of RuCl2(eta(6)-arene, eta(1)-imidazolinylidene) complexes 2a-f was evaluated in the direct arylation of 2-phenylpyridine with chlorobenzene derivatives. (C) 2009 Elsevier B. V. All rights reserved.

引用

页码：4025 / 4031

页数：7

共 102 条

[21] Redox processes involving hydrocarbylmetal (N-heterocyclic carbene) complexes and associated imidazolium salts:: ramifications for catalysis
Cavell, KJ
McGuinness, DS
[J]. COORDINATION CHEMISTRY REVIEWS, 2004, 248 (7-8) : 671 - 681
[22] GENERAL SYNTHESIS OF TRANSITION-METAL CARBENE COMPLEXES - CRO, FEO, IRI, NIII, PDII, PTII, AND AUI MONO-CARBENE AND OLIGO-CARBENE SPECIES FROM ELECTRON-RICH OLEFINS
CETINKAY.B
DIXNEUF, P
LAPPERT, MF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (06) : 206 - 206
[23] η6-mesityl,η1-imidazolinylidene-carbene-ruthenium(II) complexes:: Catalytic activity of their allenylidene derivatives in alkene metathesis and cycloisomerisation reactions
Çetinkaya, B
Demir, S
Özdemir, I
Toupet, L
Sémeril, D
Bruneau, C
Dixneuf, PH
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (10) : 2323 - 2330
[24] Synthesis and immobilization of N-heterocyclic carbene complexes of Ru(II):: catalytic activity and recyclability for the furan formation
Çetinkaya, B
Gürbüz, N
Seçkin, T
Özdemir, I
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 184 (1-2) : 31 - 38
[25] First ruthenium complexes with a chelating arene carbene ligand as catalytic precursors for alkene metathesis and cycloisomerisation
Çetinkaya, B
Demir, S
Özdemir, I
Toupet, L
Sémeril, D
Bruneau, C
Dixneuf, PH
[J]. NEW JOURNAL OF CHEMISTRY, 2001, 25 (04) : 519 - 521
[26] Synthesis and catalytic properties of N-functionalized carbene complexes of rhodium(I) and ruthenium(II)
Cetinkaya, B
Ozdemir, I
Dixneuf, PH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 534 (1-2) : 153 - 158
[27] Ruthenium-carbene catalysts for the synthesis of 2,3-dimethylfuran
Cetinkaya, B
Ozdemir, I
Bruneau, C
Dixneuf, PH
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 118 (01) : L1 - L4
[28] SYNTHESIS AND CHARACTERIZATION OF UNUSUAL TETRAAMINOALKENES (ENETETRAMINES)
CETINKAYA, E
HITCHCOCK, PB
JASIM, HA
LAPPERT, MF
SPYROPOULOS, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (05): : 561 - 567
[29] Ruthenium carbene complexes containing a triazolidene cationic ligand
Chaumonnot, A
Donnadieu, B
Sabo-Etienne, S
Chaudret, B
Buron, C
Bertrand, G
Metivier, P
[J]. ORGANOMETALLICS, 2001, 20 (26) : 5614 - 5618
[30] Selective oxidation of aliphatic C-H bonds in the synthesis of complex molecules
Christmann, Mathias
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (15) : 2740 - 2742

← 1 2 3 4 5 6 7 8 9 10 →