Blue-shift of surface plasmon resonance in a metal nanoslit array structure

被引:37
作者
Jung, Yun Suk [1 ,2 ]
Wuenschell, Jeff [1 ,2 ]
Kim, Hong Koo [1 ,2 ]
Kaur, Palwinder [3 ,4 ]
Waldeck, David H. [3 ,4 ]
机构
[1] Univ Pittsburgh, Dept Elect & Comp Engn, Pittsburgh, PA 15261 USA
[2] Univ Pittsburgh, Petersen Inst NanoSci & Engn, Pittsburgh, PA 15261 USA
[3] Univ Pittsburgh, Dept Chem, Pittsburgh, PA 15260 USA
[4] Univ Pittsburgh, Petersen Inst NanoSci & Engn, Pittsburgh, PA 15260 USA
关键词
SELF-ASSEMBLED MONOLAYERS; ANOMALOUS-DISPERSION; DYE MONOLAYER; TRANSMISSION; PROPAGATION; SLITS; LIGHT;
D O I
10.1364/OE.17.016081
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The adsorption of a self-assembled monolayer of molecules on a metal surface commonly causes a red-shift in its surface plasmon resonance. We report that the anomalous dispersion of surface plasmons in a Au nanoslit array structure can cause a blue-shift of optical transmission upon adsorption of a non-absorbing self-assembled monolayer of molecules. We develop a simple model that explains the blue-shift observed in the transmission spectra with monolayer adsorption in terms of the interplay of anomalous dispersion and the cavity resonance of surface plasmons in the nanoslit array. (C) 2009 Optical Society of America
引用
收藏
页码:16081 / 16091
页数:11
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