Electrochemical synthesis of LiTiO2 and LiTi2O4 in molten LiCl

被引：57
作者：
Jiang, K
Hu, XH
Sun, HJ
Wang, DH
Jin, XB
Ren, YY
Chen, GZ [1 ]
机构：
[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China
[2] Wuhan Univ, Ctr Electron Microscopy, Wuhan 430072, Peoples R China
[3] Univ Nottingham, Sch Chem Environm & Min Engn, Nottingham NG7 2RD, England
来源：
CHEMISTRY OF MATERIALS | 2004年 / 16卷 / 22期
关键词：
D O I：
10.1021/cm0494148
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The rock salt-type LiTiO2 and spinel-type LiTi2O4 were synthesized with accurate control of stoichiometry by electrochemical insertion of Li+ into solid TiO2 (anatase) in molten LiCl. The behavior of Li+ insertion was investigated by cyclic voltammetry using a "TiO2 powder modified molybdenum electrode". The results indicate two Li+ insertion reactions at two different potentials for the formation of LiTiO2 and LiTi2O4, respectively, as confirmed by ICP, XRD, and TEM analyses.
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收藏
页码：4324 / 4329
页数：6
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