Naked eye sensing of melamine: aggregation induced recognition by sodium D-gluconate stabilised silver nanoparticles

被引:17
作者
Kaleeswaran, Palanichamy [1 ]
Nandhini, Thanasekaran [1 ]
Pitchumani, Kasi [1 ,2 ]
机构
[1] Madurai Kamaraj Univ, Sch Chem, Dept Nat Prod Chem, Madurai 625021, Tamil Nadu, India
[2] Madurai Kamaraj Univ, Ctr Green Chem Proc, Madurai 625021, Tamil Nadu, India
关键词
TURN-ON FLUORESCENT; MOLECULARLY IMPRINTED POLYMER; ENHANCED RAMAN-SPECTROSCOPY; MODIFIED GOLD NANOPARTICLES; TANDEM MASS-SPECTROMETRY; COLORIMETRIC DETECTION; VISUAL DETECTION; QUANTUM DOTS; RAW-MILK; BETA-CYCLODEXTRIN;
D O I
10.1039/c5nj03083h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly selective, sensitive and low-cost colorimetric sensor for a biologically important analyte, namely melamine, is reported using sodium D-gluconate stabilised silver nanoparticles. Hydrogen bonding between sodium D-gluconate and melamine induces aggregation of silver nanoparticles with a consequent color change. The aggregation induced color change from yellow to red is monitored by UV-visible spectroscopy and the structure is confirmed by HRTEM. The selective sensing of melamine by sodium D-gluconate stabilised silver nanoparticles is also confirmed by competitive binding studies. The detection limit is found to be 5 x 10(-7) M (0.06 ppm) and this melamine sensor also finds applications in real sample analysis.
引用
收藏
页码:3869 / 3874
页数:6
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