A Homochiral Microporous Hydrogen-Bonded Organic Framework for Highly Enantioselective Separation of Secondary Alcohols

被引：296
|
作者：
Li, Peng [1 ]
He, Yabing [1 ]
Guang, Jie [1 ]
Weng, Linghong [2 ]
Zhao, John Cong-Gui [1 ]
Xiang, Shengchang [3 ]
Chen, Banglin [1 ]
机构：
[1] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA
[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[3] Fujian Normal Univ, Coll Chem & Mat, Fuzhou 350007, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 02期
关键词：
SELECTIVE SEPARATION; SMALL MOLECULES; NETWORK; CRYSTALS; RECOGNITION; CATALYSIS; BINDING;
D O I：
10.1021/ja4129795
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A homochiral microporous hydrogen. bonded organic framework (HOF-2) based on a BINOL derivative has been synthesized and structurally characterized to be a uninodal 6-connected {3(3)5(5)6(6)7} network. This new HOF exhibits not only a permanent porosity with the BET of 237.6 m(2) g(-1) but also, more importantly, a highly enantioselective separation of chiral secondary alcohols with ee value up to 92% for 1-phenylethanol.
引用
收藏
页码：547 / 549
页数：3
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