A Homochiral Microporous Hydrogen-Bonded Organic Framework for Highly Enantioselective Separation of Secondary Alcohols

被引：297

作者：

Li, Peng ^{[1
]}

He, Yabing ^{[1
]}

Guang, Jie ^{[1
]}

Weng, Linghong ^{[2
]}

Zhao, John Cong-Gui ^{[1
]}

Xiang, Shengchang ^{[3
]}

Chen, Banglin ^{[1
]}

机构：

[1] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[3] Fujian Normal Univ, Coll Chem & Mat, Fuzhou 350007, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 02期

关键词：

SELECTIVE SEPARATION; SMALL MOLECULES; NETWORK; CRYSTALS; RECOGNITION; CATALYSIS; BINDING;

D O I：

10.1021/ja4129795

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A homochiral microporous hydrogen. bonded organic framework (HOF-2) based on a BINOL derivative has been synthesized and structurally characterized to be a uninodal 6-connected {3(3)5(5)6(6)7} network. This new HOF exhibits not only a permanent porosity with the BET of 237.6 m(2) g(-1) but also, more importantly, a highly enantioselective separation of chiral secondary alcohols with ee value up to 92% for 1-phenylethanol.

引用

页码：547 / 549

页数：3

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