Synthesis and transformations of cyanomethyl-1,2,4,5-tetrazines

被引：6

作者：

Tolshchina, S. G. ^{[1
]}

Ishmetova, R. I. ^{[1
]}

Ignatenko, N. K. ^{[1
]}

Korotina, A. V. ^{[1
]}

Slepukhin, P. A. ^{[1
]}

Rusinov, G. L. ^{[1
]}

Charushin, V. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Ural Branch, I Ya Postovskii Inst Organ Synth, Ekaterinburg 620041, Russia

来源：

CHEMISTRY OF HETEROCYCLIC COMPOUNDS | 2013年 / 49卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

CH acids; cyanomethyltetrazine anions; ethyl cyanoacetate; 3,6-dihetaryl-1,2,4,5-tetrazines; 1,3-indanedione; malonodinitrile; pyrrolo[1,2-b][1,2,4,5]tetrazines; tetrazine coordination compounds; nucleophilic substitution; TETRAZINES; 3,6-BIS(3,5-DIMETHYL-4-R-PYRAZOL-1-YL)-1,2,4,5-TETRAZINES; 1,2,4,5-TETRAZINES;

D O I：

10.1007/s10593-013-1288-z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Derivatives of s-tetrazine containing malonodinitrile, ethyl cyanoacetate, and 1,3-indanedione fragments were synthesized by the nucleophilic substitution of heterocyclic groups in 3,6-diazolyl-1,2,4,5-tetrazines. Coordination compounds of the cyanomethyltetrazine anion with Cu+, Mn2+, and the tetrathiafulvalene radical cation were obtained, and their structures were determined. A transformation of cyanomethyltetrazines to pyrrolo[1,2-b][1, 2, 4, 5]tetrazines catalyzed by metal cations was discovered.

引用

页码：604 / 617

页数：14

共 50 条

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