Catalytic Solvolytic and Hydrolytic Degradation of Toxic Methyl Paraoxon with La(catecholate)-Functionalized Porous Organic Polymers

被引：80
|
作者：
Totten, Ryan K.
Weston, Mitchell H.
Park, Jin Kuen
Farha, Omar K. [1 ]
Hupp, Joseph T.
Nguyen, SonBinh T.
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
ACS CATALYSIS | 2013年 / 3卷 / 07期
关键词：
porous organic polymers; catechol; catalysis; organophosphates; lanthanum; FOLD ACCELERATION; GAS-STORAGE; METHANOLYSIS; DECOMPOSITION; DESTRUCTION; FRAMEWORK; TRIESTER; ROBUST; AGENTS;
D O I：
10.1021/cs4001738
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Two robust catechol-functionalized porous organic polymers (catPOPs) with different T-d-directing nodes were synthesized using a cobalt-catalyzed acetylene trimetization (CCAT) strategy. Postsynthesis metallation was readily carried out with La(acac)(3) to afford catalytically active La-functionalized catPOPs for the solvolytic and hydrolytic degradation of the toxic organophosphate compound methyl paraoxon, a simulant for nerve agents.
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收藏
页码：1454 / 1459
页数：6
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