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Cu3Pt/Cu2O nanorod array prepared by a facile method for glucose detection
被引:12
|作者:
Yang, Bingwang
[1
]
Han, Ning
[1
]
Zhang, Liying
[1
]
Yi, Shasha
[1
]
Zhang, Zongtao
[1
]
Wang, Yu
[1
]
Zhou, Ying
[1
]
Chen, Deliang
[1
]
Gao, Yanfeng
[2
]
机构:
[1] Zhengzhou Univ, Sch Mat Sci & Engn, 100 Sci Ave, Zhengzhou 450100, Henan, Peoples R China
[2] Shanghai Univ, Sch Mat Sci & Engn, 333 Nanchen Rd, Shanghai 200444, Peoples R China
关键词:
Cu3Pt/Cu2O;
Nanorod array;
Electrochemical sensor;
Glucose detector;
NONENZYMATIC GLUCOSE;
GRAPHENE OXIDE;
COPPER FOAM;
CU;
ELECTRODE;
NANOPARTICLES;
PERFORMANCE;
OXIDATION;
NANOSHEETS;
NANOARRAYS;
D O I:
10.1016/j.apsusc.2020.147596
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The combination of noble metal and transition metal oxide (TMO) can effectively expand their application in electrochemistry. However, rational design and convenient fabrication of the noble metal/TMO nanoarray is rarely reported. Here, Cu3Pt/Cu2O nanorod array was constructed on copper substrate by a convenient method and used as non-enzymatic glucose detector. In the nanorod, Moreover, the glycol ligand acted as a bridge for electron transfer from Cu2O at surface to Cu3Pt and the nanorod structure of Cu3Pt could serve as a highway for electron transfer, hence, when the Cu3Pt/Cu2O nanorod array was used as glucose detector, it delivered enhanced linear detection range (0.005-0.1 mM, 0.1-1.5 mM and 1.5-10 mM), high corresponding sensitivity (5082 mu A mM(-1) cm(-2) , 3331 mu A mM(-1) cm(-2) and 118 mu A mM(-1) cm(-2)), fast response time (< 6 s), low detection limit (1.759 mu M, S/N = 3) and high selectivity.
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页数:9
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