Cu3Pt/Cu2O nanorod array prepared by a facile method for glucose detection

被引:12
|
作者
Yang, Bingwang [1 ]
Han, Ning [1 ]
Zhang, Liying [1 ]
Yi, Shasha [1 ]
Zhang, Zongtao [1 ]
Wang, Yu [1 ]
Zhou, Ying [1 ]
Chen, Deliang [1 ]
Gao, Yanfeng [2 ]
机构
[1] Zhengzhou Univ, Sch Mat Sci & Engn, 100 Sci Ave, Zhengzhou 450100, Henan, Peoples R China
[2] Shanghai Univ, Sch Mat Sci & Engn, 333 Nanchen Rd, Shanghai 200444, Peoples R China
关键词
Cu3Pt/Cu2O; Nanorod array; Electrochemical sensor; Glucose detector; NONENZYMATIC GLUCOSE; GRAPHENE OXIDE; COPPER FOAM; CU; ELECTRODE; NANOPARTICLES; PERFORMANCE; OXIDATION; NANOSHEETS; NANOARRAYS;
D O I
10.1016/j.apsusc.2020.147596
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The combination of noble metal and transition metal oxide (TMO) can effectively expand their application in electrochemistry. However, rational design and convenient fabrication of the noble metal/TMO nanoarray is rarely reported. Here, Cu3Pt/Cu2O nanorod array was constructed on copper substrate by a convenient method and used as non-enzymatic glucose detector. In the nanorod, Moreover, the glycol ligand acted as a bridge for electron transfer from Cu2O at surface to Cu3Pt and the nanorod structure of Cu3Pt could serve as a highway for electron transfer, hence, when the Cu3Pt/Cu2O nanorod array was used as glucose detector, it delivered enhanced linear detection range (0.005-0.1 mM, 0.1-1.5 mM and 1.5-10 mM), high corresponding sensitivity (5082 mu A mM(-1) cm(-2) , 3331 mu A mM(-1) cm(-2) and 118 mu A mM(-1) cm(-2)), fast response time (< 6 s), low detection limit (1.759 mu M, S/N = 3) and high selectivity.
引用
收藏
页数:9
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