Solvent Controlled Synthesis of Tin Oxide Nanocatalysts and Their Applications in Photodegradation of Environmental Hazardous Materials

被引:8
作者
Muneer, Iqra [1 ]
Farrukh, Muhammad Akhyar [1 ]
Shaghraf [1 ]
Khaleeq-ur-Rahmanl, Muhammad [1 ]
Umar, Akrajas Ali [1 ]
Adnan, Rohana [1 ]
机构
[1] GC Univ Lahore, Dept Chem, Lahore 54000, Pakistan
来源
ISESCO CONFERENCE ON NANOMATERIALS AND APPLICATIONS 2012 | 2013年 / 756卷
关键词
Nanocatalysts; tin oxide; photocatalysis; solvent; pollutants; SIZE-CONTROLLED SYNTHESIS; SNO2; NANOPARTICLES; MONODISPERSED SNO2; GAS SENSOR; ANODIZATION; METAL;
D O I
10.4028/www.scientific.net/MSF.756.197
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Solvent controlled synthesis of tin oxide nanocatalysts were prepared via the hydrothermal method. To study the effect of solvent on the particle size of tin oxide and their catalytic efficiency on photodegradation of environmental hazardous materials, the synthesis was carried out at different concentrations of solvent (isoamyl alcohol) keeping all other reaction conditions constant. The nanoparticles were characterized by Fourier Transmission Infrared Spectroscopy, Scanning Electron Microscopy, Transmission Electron Microscopy, X-ray Diffraction and Thermogravimeteric analysis. Prepared nanoparticles were applied as nanocatalyst under UV-visible light for the photodegradation of methyl green, which is an abundant organic pollutant of industrial waste water. Photodegradation activities of the nanocatalysts were measured in three different ways, i. pseudo first order rate constant, "k". ii. percentage degradation and iii. degradation rate. Effect of solvent was quantitatively explained in term of double sphere model of ion-ion interaction. Degradation of pollutants was also monitored by High Performance Liquid Chromatography.
引用
收藏
页码:197 / +
页数:2
相关论文
共 26 条
  • [1] Synthesis and Characterization of High Surface Area Tin Oxide Nanoparticles via the Sol-Gel Method as a Catalyst for the Hydrogenation of Styrene
    Adnan, Rohana
    Razana, Nur Ariesma
    Rahman, Ismail Abdul
    Farrukh, Muhammad Akhyar
    [J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2010, 57 (02) : 222 - 229
  • [2] Anandan K, 2010, J NON-OXIDE GLASSES, V2, P83
  • [3] Synthesis of ZnO nanoparticles by hydrothermal method
    Aneesh, P. M.
    Vanaja, K. A.
    Jayaraj, M. K.
    [J]. NANOPHOTONIC MATERIALS IV, 2007, 6639
  • [4] Mechanistic studies of the photocatalytic degradation of methyl green: An investigation of products of the decomposition processes
    Chen, Chiing-Chang
    Lu, Chung-Shin
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2007, 41 (12) : 4389 - 4396
  • [5] α-Fe2O3 nanotubes in gas sensor and lithium-ion battery applications
    Chen, J
    Xu, LN
    Li, WY
    Gou, XL
    [J]. ADVANCED MATERIALS, 2005, 17 (05) : 582 - +
  • [6] Chemical vapor deposition of SnO2 thin films from bis(β-diketonato)tin complexes
    Chi, KM
    Lin, CC
    Lu, YH
    Liao, JH
    [J]. JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2000, 47 (03) : 425 - 431
  • [7] Fully transparent thin-film transistor devices based on SnO2 nanowires
    Dattoli, Eric N.
    Wan, Qing
    Guo, Wei
    Chen, Yanbin
    Pan, Xiaoqing
    Lu, Wei
    [J]. NANO LETTERS, 2007, 7 (08) : 2463 - 2469
  • [8] Farrukh M. A., 2003, THESIS
  • [9] Preparation and characterization of zinc oxide nanoflakes using anodization method and their photodegradation activity on methylene blue
    Farrukh, Muhammad Akhyar
    Thong, Chin-Kiat
    Adnan, Rohana
    Kamarulzaman, Mohd Amirrul
    [J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 86 (13) : 2041 - 2048
  • [10] Influence of reaction parameters on the synthesis of surfactant-assisted tin oxide nanoparticles
    Farrukh, Muhammad Akhyar
    Tan, Prisca
    Adnan, Rohana
    [J]. TURKISH JOURNAL OF CHEMISTRY, 2012, 36 (02) : 303 - 314