Lowpressure chemical vapor deposition synthesis of hexagonal boron nitride on polycrystalline metal foils

被引:27
作者
Gibb, Ashley [1 ,2 ,3 ]
Alem, Nasim [2 ,3 ]
Zettl, Alex [2 ,4 ]
机构
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
[4] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Natl Ctr Electron Microscopy, Berkeley, CA 94720 USA
来源
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS | 2013年 / 250卷 / 12期
关键词
chemical vapor deposition; h-BN; hexagonal boron nitride; GRAPHENE FILMS; HIGH-QUALITY; MONOLAYER; LAYER; NANOTUBES; GROWTH; GRAPHITE; NI(111);
D O I
10.1002/pssb.201300088
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The two-dimensional sp(2)-bonded material hexagonal boron nitride (h-BN) has unique electronic, thermal, mechanical, and chemical properties. It has recently found use as an ideal substrate for graphene-based electronic devices. We here describe synthesis of mono- to few-layer h-BN films using low pressure chemical vapor deposition (LPCVD) from borazine, with nickel, copper and platinum employed as catalytic substrates, and transfer of some of these films using a non-polymer method. Characterization of the films via Raman spectroscopy and transmission electron microscopy (TEM) is performed. Chemical vapor deposition synthesis of hexagonal boron nitride from borazine using metallic substrates. (C) 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:2727 / 2731
页数:5
相关论文
共 37 条
[1]   Vacancy growth and migration dynamics in atomically thin hexagonal boron nitride under electron beam irradiation [J].
Alem, Nasim ;
Erni, Rolf ;
Kisielowski, Christian ;
Rossell, Marta D. ;
Hartel, Peter ;
Jiang, Bin ;
Gannett, Will ;
Zettl, A. .
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2011, 5 (08) :295-297
[2]   XPD and STM investigation of hexagonal boron nitride on Ni(111) [J].
Auwärter, W ;
Kreutz, TJ ;
Greber, T ;
Osterwalder, J .
SURFACE SCIENCE, 1999, 429 (1-3) :229-236
[3]  
Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]
[4]   An attempt to identify the presence of polytype stacking faults in hBN powders by means of X-ray diffraction [J].
Balint, M. G. ;
Petrescu, M. I. .
DIAMOND AND RELATED MATERIALS, 2009, 18 (09) :1157-1162
[5]  
Balmain W.H., 1842, J PRAKT CHEM, V27, P422, DOI [DOI 10.1002/PRAC.18420270164, 10.1002/prac.18420270164]
[6]   BORON-NITRIDE NANOTUBES [J].
CHOPRA, NG ;
LUYKEN, RJ ;
CHERREY, K ;
CRESPI, VH ;
COHEN, ML ;
LOUIE, SG ;
ZETTL, A .
SCIENCE, 1995, 269 (5226) :966-967
[7]   Mass-production of boron nitride double-wall nanotubes and nanococoons [J].
Cumings, J ;
Zettl, A .
CHEMICAL PHYSICS LETTERS, 2000, 316 (3-4) :211-216
[8]   Longitudinal Splitting of Boron Nitride Nanotubes for the Facile Synthesis of High Quality Boron Nitride Nanoribbons [J].
Erickson, Kris J. ;
Gibb, Ashley L. ;
Sinitskii, Alexander ;
Rousseas, Michael ;
Alem, Nasim ;
Tour, James M. ;
Zettl, Alex K. .
NANO LETTERS, 2011, 11 (08) :3221-3226
[9]   Boron nitride substrates for high mobility chemical vapor deposited graphene [J].
Gannett, W. ;
Regan, W. ;
Watanabe, K. ;
Taniguchi, T. ;
Crommie, M. F. ;
Zettl, A. .
APPLIED PHYSICS LETTERS, 2011, 98 (24)
[10]   Repeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinum [J].
Gao, Libo ;
Ren, Wencai ;
Xu, Huilong ;
Jin, Li ;
Wang, Zhenxing ;
Ma, Teng ;
Ma, Lai-Peng ;
Zhang, Zhiyong ;
Fu, Qiang ;
Peng, Lian-Mao ;
Bao, Xinhe ;
Cheng, Hui-Ming .
NATURE COMMUNICATIONS, 2012, 3