Lewis acidity of boron compounds

被引：267
作者：
Sivaev, Igor B. [1 ]
Bregadze, Vladimir I. [1 ]
机构：
[1] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, 28 Vavilov Str, Moscow 119991, Russia
来源：
COORDINATION CHEMISTRY REVIEWS | 2014年 / 270卷
基金：
俄罗斯基础研究基金会;
关键词：
Boron; Lewis acidity; Structure-property relationships; Acidity scale; SITE OLEFIN POLYMERIZATION; FLUORIDE IONS; MOLECULAR-STRUCTURE; HETEROLYTIC ACTIVATION; COORDINATION CHEMISTRY; DIHYDROGEN ACTIVATION; PERFLUOROARYL BORANES; CATIONIC BORANES; ANION-BINDING; CYANIDE IONS;
D O I：
10.1016/j.ccr.2013.10.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The effects of different electronic and structural factors in determining the Lewis acidity of boron compounds are analyzed. Scales of Lewis acidity for boron Lewis acids based on the Gutmann-Beckett and Childs methods have been constructed using data available in the literature. The Lewis acidities of transient boron Lewis acids have been estimated and their high Lewis acidity has been confirmed. (c) 2013 Elsevier B.V. All rights reserved.
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收藏
页码：75 / 88
页数：14
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