Nylon 610 and carbon nanotube composite by in situ interfacial polymerization

被引：83

作者：

Kang, Minsung ^{[1
]}

Myung, Seung Jun ^{[1
]}

Jin, Hyoung-Joon ^{[1
]}

机构：

[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea

来源：

POLYMER | 2006年 / 47卷 / 11期

关键词：

carbon nanotube; interfacial polymerization; nylon; 610;

D O I：

10.1016/j.polymer.2006.03.073

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(hexamethylenesebacamide) (nylon 610) nanocomposites containing well dispersed multi-walled carbon nanotubes (MWNTs) were successfully produced via the in situ inter-facial polymerization of two liquid phases, one containing hexamethylenediamine in the presence of MWNTs and the other containing sebacoyl chloride. The processing consisted of dispersing acid-treated MWNTs in an aqueous phase containing a Triton X-100 surfactant. Scanning and transmittance electron microscopies showed that the individual MWNTs were uniformly dispersed in the nylon 610 matrix. Tensile tests of the composite sheet showed a 170% increase in the Young's modulus with slight increases in the tensile strength and the elongation at break (about 40 and 25%, respectively). This suggests an interaction between the acid-treated MWNTs and nylon 610. The thermal stability of the composite was also enhanced by the incorporation of MWNT into nylon 610 matrix. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：3961 / 3966

页数：6

共 64 条

[1]

Ajayan PM, 2000, ADV MATER, V12, P750, DOI 10.1002/(SICI)1521-4095(200005)12:10<750::AID-ADMA750>3.0.CO

[2]

2-6

[3] ALIGNED CARBON NANOTUBE ARRAYS FORMED BY CUTTING A POLYMER RESIN-NANOTUBE COMPOSITE [J].

AJAYAN, PM ;

STEPHAN, O ;

COLLIEX, C ;

TRAUTH, D .

SCIENCE, 1994, 265 (5176) :1212-1214

[4] Stabilization of individual carbon nanotubes in aqueous solutions [J].

Bandyopadhyaya, R ;

Nativ-Roth, E ;

Regev, O ;

Yerushalmi-Rozen, R .

NANO LETTERS, 2002, 2 (01) :25-28

[5] Carbon nanotubes - the route toward applications [J].

Baughman, RH ;

Zakhidov, AA ;

de Heer, WA .

SCIENCE, 2002, 297 (5582) :787-792

[6] Heat capacity of carbon nanotubes [J].

Benedict, LX ;

Louie, SG ;

Cohen, ML .

SOLID STATE COMMUNICATIONS, 1996, 100 (03) :177-180

[7] Unusually high thermal conductivity of carbon nanotubes [J].

Berber, S ;

Kwon, YK ;

Tománek, D .

PHYSICAL REVIEW LETTERS, 2000, 84 (20) :4613-4616

[8] INTERFACIAL SYNTHESIS IN THE PREPARATION OF REVERSE-OSMOSIS MEMBRANES [J].

CADOTTE, JE ;

KING, RS ;

MAJERLE, RJ ;

PETERSEN, RJ .

JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1981, A15 (05) :727-755

[9] Solution properties of single-walled carbon nanotubes [J].

Chen, J ;

Hamon, MA ;

Hu, H ;

Chen, YS ;

Rao, AM ;

Eklund, PC ;

Haddon, RC .

SCIENCE, 1998, 282 (5386) :95-98

[10] Non-destructive purification of multi-walled carbon nanotubes produced by catalyzed CVD [J].

Chen, XH ;

Chen, CS ;

Chen, Q ;

Cheng, FQ ;

Zhang, G ;

Chen, ZZ .

MATERIALS LETTERS, 2002, 57 (03) :734-738

← 1 2 3 4 5 6 7 →